ICCAS OpenIR
POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS
Li, Yan-guo; Liu, Jing-yu; Li, Yue-sheng
2010
Source PublicationCHINESE JOURNAL OF POLYMER SCIENCE
ISSN0256-7679
Volume28Issue:1Pages:101-106
AbstractA simple and effective way to prepare poly(acrylate)s, such as poly(methacrylate), poly(butyl acrylate) and poly(butyl methacrylate), has been achieved by using the single component aluminum-based compounds, such as modified methylaluminoxane (MMAO), triisobutylaluminium (TIBA) and triethylaluminium (TEA) as initiators. Effective initiations and high molecular weight polymers with unimodal molecular weight distributions could be easily obtained by varying the reaction parameters of systems under mild conditions. Although these aluminum compounds were inefficient initiators for methyl methacrylate (MMA) polymerization, they exhibited remarkable catalytic activity for butyl methacrylate (BMA) polymerization, affording high molecular weight poly(BMA)s.
KeywordPolymerization Catalysts (Meth)Acrylate
DOI10.1007/s10118-010-8219-6
Indexed BySCI
Language英语
WOS IDWOS:000279111200013
PublisherSPRINGER
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69770
Collection中国科学院化学研究所
Corresponding AuthorLi, Yue-sheng
AffiliationChinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Li, Yan-guo,Liu, Jing-yu,Li, Yue-sheng. POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2010,28(1):101-106.
APA Li, Yan-guo,Liu, Jing-yu,&Li, Yue-sheng.(2010).POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS.CHINESE JOURNAL OF POLYMER SCIENCE,28(1),101-106.
MLA Li, Yan-guo,et al."POLYMERIZATION OF (METH)ACRYLATES WITH ALUMINUM-BASED INITIATORS".CHINESE JOURNAL OF POLYMER SCIENCE 28.1(2010):101-106.
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