ICCAS OpenIR
Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate
Liang, Lei1; Rao, Guodong1; Sun, Hao-Ling2; Zhang, Jun-Long1
2010-10-04
Source PublicationADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
Volume352Issue:14-15Pages:2371-2377
AbstractWe have developed a new protocol involving the "copper(II) chloride-cesium carbonate" system for the aerobic oxidation of primary alcohols. Cesium carbonates and the solvents such as toluene and 1,2-dichloroethane play important roles to form a catalytically active intermediate containing a mu-hydroxyl-bridged trinuclear copper moiety (complex 1). From the X-ray crystal structure of complex 1, an electrostatic interaction between chloride anions and cesium cations was observed, which stimulated us to understand the roles of cesium carbonate in this reaction as a base, stabilizing and "solvating" intermediates in toluene and 1,2-dichloroethane.
KeywordAerobic Oxidation Copper Catalysis Intermediates Primary Alcohols
DOI10.1002/adsc.201000456
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000284003100004
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:24[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69716
Collection中国科学院化学研究所
Corresponding AuthorZhang, Jun-Long
Affiliation1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
2.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China
Recommended Citation
GB/T 7714
Liang, Lei,Rao, Guodong,Sun, Hao-Ling,et al. Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(14-15):2371-2377.
APA Liang, Lei,Rao, Guodong,Sun, Hao-Ling,&Zhang, Jun-Long.(2010).Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate.ADVANCED SYNTHESIS & CATALYSIS,352(14-15),2371-2377.
MLA Liang, Lei,et al."Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active mu-Hydroxyl-Bridged Trinuclear Copper Intermediate".ADVANCED SYNTHESIS & CATALYSIS 352.14-15(2010):2371-2377.
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