ICCAS OpenIR
Efficient in situ three-component formation of chiral oxazoline-Schiff base copper(II) complexes: towards combinatorial library of chiral catalysts for asymmetric Henry reaction
Yang, Wen1; Liu, Han2; Du, Da-Ming1
2010
Source PublicationORGANIC & BIOMOLECULAR CHEMISTRY
ISSN1477-0520
Volume8Issue:13Pages:2956-2960
AbstractA combinatorial in situ three-component chiral oxazoline-Schiff base copper(II) complex catalyst formation method was developed. This simple combinatorial chiral catalyst approach provided a modular library of chiral oxazoline-Schiff base copper(II) complex catalysts. The catalytic activity of these in situ generated catalysts can be rapidly and conveniently evaluated in the asymmetric Henry reaction. Moderate to good yields and enantioselectivities (up to 92% ee) were obtained under the optimized condition. The combination of modular three-component catalyst formation and in situ asymmetric reaction provides a new technology in asymmetric catalysis.
DOI10.1039/b923835b
Indexed BySCI ; IC
Language英语
WOS IDWOS:000278824700010
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69652
Collection中国科学院化学研究所
Corresponding AuthorDu, Da-Ming
Affiliation1.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
2.Peking Univ, BNLMS, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Yang, Wen,Liu, Han,Du, Da-Ming. Efficient in situ three-component formation of chiral oxazoline-Schiff base copper(II) complexes: towards combinatorial library of chiral catalysts for asymmetric Henry reaction[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2010,8(13):2956-2960.
APA Yang, Wen,Liu, Han,&Du, Da-Ming.(2010).Efficient in situ three-component formation of chiral oxazoline-Schiff base copper(II) complexes: towards combinatorial library of chiral catalysts for asymmetric Henry reaction.ORGANIC & BIOMOLECULAR CHEMISTRY,8(13),2956-2960.
MLA Yang, Wen,et al."Efficient in situ three-component formation of chiral oxazoline-Schiff base copper(II) complexes: towards combinatorial library of chiral catalysts for asymmetric Henry reaction".ORGANIC & BIOMOLECULAR CHEMISTRY 8.13(2010):2956-2960.
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