ICCAS OpenIR
One Step Synthesis of Chiral Olefins via Asymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions
Hu, Xichao; Cao, Ziping; Liu, Zhaoqun; Wang, Yazhou; Du, Haifeng
2010-03-01
Source PublicationADVANCED SYNTHESIS & CATALYSIS
ISSN1615-4150
Volume352Issue:4Pages:651-655
AbstractA variety of acyclic chiral dienes were synthesized in a single step via palladium(0)-catalyzed asymmetric allylic and homoallylic C-H diamination of terminal olefins. The applications of such simple dienes as steering ligands for rhodium(1)-catalyzed asymmetric 1,4-additions afforded the corresponding adducts in excellent yields and up to 85% ee.
KeywordAcyclic Chiral Dienes Asymmetric Catalysis Asymmetric Diamination Conjugated Addition Diene Ligands
DOI10.1002/adsc.200900693
Indexed BySCI ; IC
Language英语
WOS IDWOS:000276052100010
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:35[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69614
Collection中国科学院化学研究所
Corresponding AuthorDu, Haifeng
AffiliationChinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Hu, Xichao,Cao, Ziping,Liu, Zhaoqun,et al. One Step Synthesis of Chiral Olefins via Asymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(4):651-655.
APA Hu, Xichao,Cao, Ziping,Liu, Zhaoqun,Wang, Yazhou,&Du, Haifeng.(2010).One Step Synthesis of Chiral Olefins via Asymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions.ADVANCED SYNTHESIS & CATALYSIS,352(4),651-655.
MLA Hu, Xichao,et al."One Step Synthesis of Chiral Olefins via Asymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions".ADVANCED SYNTHESIS & CATALYSIS 352.4(2010):651-655.
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