ICCAS OpenIR
H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra
Cong, Rihong; Yang, Tao; Li, Hongmei; Liao, Fuhui; Wang, Yingxia; Lin, Jianhua
2010-04-01
Source PublicationEUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN1434-1948
Issue11Pages:1703-1709
AbstractH2InB5O10, a new hydrated indium pentaborate, was prepared by the boric acid flux method and characterized by IR, solid-state B-11 MAS NMR and H-1 CRAMPS NMR spectroscopy. Its structure was determined by powder X-ray diffraction and refined by Rietveld analysis. H2InB5O10 crystallizes in the monoclinic space group C2. The structure features a new 2D tetrahedrally four-connected borate network constructed from a new pentaborate fundamental building block, B5O14. The 2D borate network is formed by two 6(3) borate layers linked by additional BO4 groups in a spiro-5 mode and then combines with InO6 octahedra to give rise to the 3D structure of H2InB5O10. The strong hydrogen bonds that cross-link oxygen atoms of additional BO4 groups between the borate layers help to stabilize the borate network.
KeywordBorates Indium X-ray Diffraction Network Structures Hydrogen Bonds
DOI10.1002/ejic.200901078
Indexed BySCI
Language英语
WOS IDWOS:000277210400016
PublisherWILEY-BLACKWELL
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69440
Collection中国科学院化学研究所
Corresponding AuthorWang, Yingxia
AffiliationPeking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Cong, Rihong,Yang, Tao,Li, Hongmei,et al. H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2010(11):1703-1709.
APA Cong, Rihong,Yang, Tao,Li, Hongmei,Liao, Fuhui,Wang, Yingxia,&Lin, Jianhua.(2010).H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(11),1703-1709.
MLA Cong, Rihong,et al."H2InB5O10: A New Pentaborate Constructed from 2D Tetrahedrally Four-Connected Borate Layers and InO6 Octahedra".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .11(2010):1703-1709.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Cong, Rihong]'s Articles
[Yang, Tao]'s Articles
[Li, Hongmei]'s Articles
Baidu academic
Similar articles in Baidu academic
[Cong, Rihong]'s Articles
[Yang, Tao]'s Articles
[Li, Hongmei]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Cong, Rihong]'s Articles
[Yang, Tao]'s Articles
[Li, Hongmei]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.