ICCAS OpenIR
2-(1H-2-Benzimidazolyl)-6-(1-(arylimino)ethyl)pyridylnickel Complexes: Synthesis, Characterization, and Ethylene Oligomerization
Xiao, Liwei1; Zhang, Min2; Gao, Rong2; Cao, Xiaoping1; Sun, Wen-Hua1,2
2010
Source PublicationAUSTRALIAN JOURNAL OF CHEMISTRY
ISSN0004-9425
Volume63Issue:1Pages:109-115
AbstractA series of tridentate N,N,N-nickel complexes bearing 2-(1H-2-benzimidazolyl)-6-(1-(arylimino)ethyl) pyridines was synthesized and characterized by elemental and IR spectroscopic analysis. The molecular structures of representative complexes were determined by single-crystal diffraction, and these were found to have a six-coordinate distorted octahedral geometry around the Ni centre. On treatment with Et(2)AlCl, all nickel complexes exhibited good catalytic activities up to 10(6) g mol(-1)(Ni) h(-1) for ethylene oligomerization with major dimerization. The steric and electronic effects on catalytic activities of metal complexes as well as the influence of various reaction parameters were carefully investigated.
DOI10.1071/CH09168
Indexed BySCI
Language英语
WOS IDWOS:000273396200015
PublisherCSIRO PUBLISHING
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69386
Collection中国科学院化学研究所
Corresponding AuthorCao, Xiaoping
Affiliation1.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Xiao, Liwei,Zhang, Min,Gao, Rong,et al. 2-(1H-2-Benzimidazolyl)-6-(1-(arylimino)ethyl)pyridylnickel Complexes: Synthesis, Characterization, and Ethylene Oligomerization[J]. AUSTRALIAN JOURNAL OF CHEMISTRY,2010,63(1):109-115.
APA Xiao, Liwei,Zhang, Min,Gao, Rong,Cao, Xiaoping,&Sun, Wen-Hua.(2010).2-(1H-2-Benzimidazolyl)-6-(1-(arylimino)ethyl)pyridylnickel Complexes: Synthesis, Characterization, and Ethylene Oligomerization.AUSTRALIAN JOURNAL OF CHEMISTRY,63(1),109-115.
MLA Xiao, Liwei,et al."2-(1H-2-Benzimidazolyl)-6-(1-(arylimino)ethyl)pyridylnickel Complexes: Synthesis, Characterization, and Ethylene Oligomerization".AUSTRALIAN JOURNAL OF CHEMISTRY 63.1(2010):109-115.
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