ICCAS OpenIR
Promoted H-2 Generation from NH3BH3 Thermal Dehydrogenation Catalyzed by Metal-Organic Framework Based Catalysts
Li, Yaoqi; Song, Ping; Zheng, Jie; Li, Xingguo
2010
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
Volume16Issue:35Pages:10887-10892
AbstractThe application of ammonium borane (AB) as a hydrogen storage material is limited by the sluggish kinetics of H, release. Two catalysts based on metal organic frameworks (MOFs) have been prepared either by applying MOF as precursors or by the in situ reduction method. In the release of H-2 from AB, the high H-2 content of the whole system, the remarkably lower reaction onset temperature, the significantly increased 117 release rates at <= 90 degrees C, and the decreased reaction exothermicity have all been achieved with only 1.0 mol% MOF-based catalyst. Moreover, the clear catalytic diversity of three catalysts has been observed and discussed. The in situ synthesized Ni-0 sites and the MOF supports in the catalysts were proven to show significant and different effects to promote the catalytic activities. With MOF-based catalysts, both the enhanced kinetics and the high H-2 capacity of the AB system present great advantages for future use.
KeywordHeterogeneous Catalysis Hydrogen Materials Science Metal-organic Frameworks
DOI10.1002/chem.201000391
Indexed BySCI
Language英语
WOS IDWOS:000282910900035
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:40[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69248
Collection中国科学院化学研究所
Corresponding AuthorLi, Xingguo
AffiliationPeking Univ, Coll Chem & Mol Engn, BNLMS, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Li, Yaoqi,Song, Ping,Zheng, Jie,et al. Promoted H-2 Generation from NH3BH3 Thermal Dehydrogenation Catalyzed by Metal-Organic Framework Based Catalysts[J]. CHEMISTRY-A EUROPEAN JOURNAL,2010,16(35):10887-10892.
APA Li, Yaoqi,Song, Ping,Zheng, Jie,&Li, Xingguo.(2010).Promoted H-2 Generation from NH3BH3 Thermal Dehydrogenation Catalyzed by Metal-Organic Framework Based Catalysts.CHEMISTRY-A EUROPEAN JOURNAL,16(35),10887-10892.
MLA Li, Yaoqi,et al."Promoted H-2 Generation from NH3BH3 Thermal Dehydrogenation Catalyzed by Metal-Organic Framework Based Catalysts".CHEMISTRY-A EUROPEAN JOURNAL 16.35(2010):10887-10892.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, Yaoqi]'s Articles
[Song, Ping]'s Articles
[Zheng, Jie]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, Yaoqi]'s Articles
[Song, Ping]'s Articles
[Zheng, Jie]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, Yaoqi]'s Articles
[Song, Ping]'s Articles
[Zheng, Jie]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.