ICCAS OpenIR
Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands
Wang, Zhuo1; Xing, Yong-Heng1; Wang, Chun-Guang1; Sun, Li-Xian2; Zhang, Jian2; Ge, Mao-Fa3; Niu, Shu-Yun1
2010
Source PublicationCRYSTENGCOMM
ISSN1466-8033
Volume12Issue:3Pages:762-773
AbstractA series of lanthanide coordination polymers, namely, [Ln(ox)(0.5)(phth)(H2O)(2)]center dot 0.5H(2)O (Ln = Tb (1), Sm (2); H(2)ox = oxalic acid; H(2)phth = 1,2-benzenedicarboxylic acid), [Ln(mal)(0.5)(phth)(H2O)(2)]center dot H2O (Ln = Eu (3), Sm (4); H(2)mal = maleic acid), [Pr-3(mal')(phth)(3)(H2O)(3)]center dot H2O (5) (H(2)mal' = malic acid) [Eu(ad)(0.5)(phth)(H2O)(2)] (Ln = Eu (6), Sm (7); H(2)ad = adipic acid), [Pr-2(ad)(phth)(2)(H2O)(4)] (8) have been synthesized hydrothermally from the self-assembly of the lanthanide ions (Ln(3+)) with different types of flexible dicarboxylate ligands and the rigid 1,2-benzenedicarboxylate ligand. All coordination polymers were characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Structural analyses reveal that the networks of all eight complexes exhibit a variety of coordination modes at the metal centers. The thermal stabilities for 1, 3, 5, 6, 8, photoluminescent properties for 1-4 and 6-7 were examined, and the results show that the complexes seem to be good candidates for novel hybrid inorganic-organic photoactive materials with excellent thermal stability.
DOI10.1039/b916127a
Indexed BySCI
Language英语
WOS IDWOS:000274773900022
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:48[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69232
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Zhuo,Xing, Yong-Heng,Wang, Chun-Guang,et al. Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands[J]. CRYSTENGCOMM,2010,12(3):762-773.
APA Wang, Zhuo.,Xing, Yong-Heng.,Wang, Chun-Guang.,Sun, Li-Xian.,Zhang, Jian.,...&Niu, Shu-Yun.(2010).Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands.CRYSTENGCOMM,12(3),762-773.
MLA Wang, Zhuo,et al."Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands".CRYSTENGCOMM 12.3(2010):762-773.
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