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Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP
Huang, Huahua; Niu, Hui; Dong, Jin Yong
2010-12-15
Source PublicationJOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN0887-624X
Volume48Issue:24Pages:5783-5789
AbstractThis article demonstrates a facile and efficient method to combine olefin coordination polymerization with atom transfer radical polymerization (ATRP) for the synthesis of isotactic polypropylene (i PP) based functional diblock copolymers The chemistry involves a styryl capped i PP pre cursor prepared through the controlled consecutive chain transfer reaction first to 1 2 bis(4 vinylphenyl)ethane and then to hydrogen in propylene polymerization mediated by an isospecific metallocene catalyst The i PP precursor can be quantitatively transformed into i PP terminated with a 1 chlor oethylbezene group (i PP t Cl) by a straightforward hydro chlorination process using hydrogen chloride With the resultant i PP t Cl as a macroinitiator of ATRP methyl meth acrylate (MMA) polymerization was exemplified in the presence of CuBr/pentamethyldiethylenetriamine preparing i PP b-PMMA copolymers of different PMMA contents (c) 2010 Wiley Periodicals Inc J Polym Sci Part A Polym Chem 48 5783-5789 2010
KeywordAtom Transfer Radical Polymerization (Atrp) Block Copolymers Chain End Functionalization Diblock Copolymer Polyolefins Polypropylene
DOI10.1002/pola.24386
Indexed BySCI
Language英语
WOS IDWOS:000285485700017
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69214
Collection中国科学院化学研究所
Corresponding AuthorNiu, Hui
AffiliationChinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Huang, Huahua,Niu, Hui,Dong, Jin Yong. Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2010,48(24):5783-5789.
APA Huang, Huahua,Niu, Hui,&Dong, Jin Yong.(2010).Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,48(24),5783-5789.
MLA Huang, Huahua,et al."Synthesis of i-PP-Based Functional Block Copolymer by a Facile Combination of Styryl-Capped i-PP and ATRP".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 48.24(2010):5783-5789.
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