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Characterization of PBT/POSS Nanocomposites Prepared by In Situ Polymerization of Cyclic Poly(butylene terephthalate) Initiated by Functionalized POSS
Wu, Fumei2,3; Xie, Tingxiu1; Yang, Guisheng1
2010-08-15
Source PublicationJOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
ISSN0887-6266
Volume48Issue:16Pages:1853-1859
AbstractNovel poly(butylene terephthalate) (PBT)/polyhedral oligomeric silsesquioxane (POSS) nanocomposites were synthesized by ring-opening polymerization of cyclic poly(butylene terephthalate) initiated by functionalized POSS with various feed ratios. The impact of PUSS incorporation on melting and crystallization behaviors of PBT/POSS nanocomposites was investigated by means of X-ray diffraction and differential scanning calorimetry. It was found that the novel organic-inorganic association result in the significant alterations in the melting and crystallization behavior of PBT. Thermal studies confirmed that the incorporation of POSS can enhance the thermal stability of the polymers, and the copolymer glass transition temperature increased with the increasing of POSS macromonomer content. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1853-1859, 2010
KeywordCopolymerization Crystallization Nanocomposites Polyhedral Oligomeric Silsesquioxane Poly(Butylene Terephthalate) Ring-opening Polymerization
DOI10.1002/polb.22060
Indexed BySCI
Language英语
WOS IDWOS:000280567500010
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69190
Collection中国科学院化学研究所
Corresponding AuthorYang, Guisheng
Affiliation1.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wu, Fumei,Xie, Tingxiu,Yang, Guisheng. Characterization of PBT/POSS Nanocomposites Prepared by In Situ Polymerization of Cyclic Poly(butylene terephthalate) Initiated by Functionalized POSS[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2010,48(16):1853-1859.
APA Wu, Fumei,Xie, Tingxiu,&Yang, Guisheng.(2010).Characterization of PBT/POSS Nanocomposites Prepared by In Situ Polymerization of Cyclic Poly(butylene terephthalate) Initiated by Functionalized POSS.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,48(16),1853-1859.
MLA Wu, Fumei,et al."Characterization of PBT/POSS Nanocomposites Prepared by In Situ Polymerization of Cyclic Poly(butylene terephthalate) Initiated by Functionalized POSS".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 48.16(2010):1853-1859.
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