ICCAS OpenIR
Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water
Wu, Suxiang; Fan, Honglei; Xie, Ye; Cheng, Yan; Wang, Qian; Zhang, Zhaofu; Han, Buxing
2010
Source PublicationGREEN CHEMISTRY
ISSN1463-9262
Volume12Issue:7Pages:1215-1219
AbstractThe CO2-water system has the potential to serve as a substitute for mineral acids for some reactions in acidic media. In this work, two reactions under hydrothermal conditions with and without CO2 were studied-the conversion of inulin to 5-hydroxymethylfurfural (5-HMF), and the hydrolysis of propylene oxide to 1,2-propanediol (1,2-PDO). The effects of CO2 pressure, reaction temperature and reactant concentration on the yield of 5-HMF and 1,2-PDO were examined. It was demonstrated that CO2 could increase the yields of 5-HMF and 1,2-PDO considerably under optimized conditions. The methods to prepare 5-HMF and 1,2-PDO are greener, in that conventional acids are not required and the solution is neutralized automatically after depressurization.
DOI10.1039/c002553d
Indexed BySCI
Language英语
WOS IDWOS:000279566300014
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:48[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69134
Collection中国科学院化学研究所
Corresponding AuthorWu, Suxiang
AffiliationChinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wu, Suxiang,Fan, Honglei,Xie, Ye,et al. Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water[J]. GREEN CHEMISTRY,2010,12(7):1215-1219.
APA Wu, Suxiang.,Fan, Honglei.,Xie, Ye.,Cheng, Yan.,Wang, Qian.,...&Han, Buxing.(2010).Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water.GREEN CHEMISTRY,12(7),1215-1219.
MLA Wu, Suxiang,et al."Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water".GREEN CHEMISTRY 12.7(2010):1215-1219.
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