ICCAS OpenIR
Synthesis, Structures, and Magnetism of Three 1D Mn-III Chains with Oxazoline-Based Ligands
Zhang, Yan1,2; Wang, Xiu-Teng3; Zhang, Xiao-Man1,2; Liu, Tian-Fu1,2; Xu, Wen-Guo1,2; Gao, Song3
2010-07-05
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume49Issue:13Pages:5868-5875
AbstractThree novel Mn-III polymers, Mn(phox)(2)(N-3)](n) (1), [Mn(Etphox)(2)(N-3)](n) (2), and [Mn(Etphox)(2)(C2N3)](n) (3), using achiral ligand Hphox (Hphox = 2-(4,5-dihydrooxazol-2-yl)phenol) and chiral ligand HEtphox (HEtphox = 2-(4-ethyl-4,5-dihydrooxazol-2-yl)phenol) were synthesized and structurally and magnetically characterized. All complexes are of 1D chain structures and form 2D frameworks by weak interactions. The adjacent 1D chains of complex 1 are connected by face-to-face.pi-pi interactions, C-H center dot center dot center dot pi interactions, and hydrogen bonding, which leads to the formation of a supramolecular 2D sheet structure. The three compounds show antiferromagnetic coupling between Mn-III ions. And compound 2 is a spin-canted weak ferromagnet with T-N=5.6 K, showing metamagnetic behavior with a two-step magnetic phase transition.
DOI10.1021/ic100006a
Indexed BySCI
Language英语
WOS IDWOS:000279211500016
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69034
Collection中国科学院化学研究所
Corresponding AuthorLiu, Tian-Fu
Affiliation1.Beijing Inst Technol, Inst Chem Phys, Dept Chem, Beijing 100081, Peoples R China
2.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
3.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Yan,Wang, Xiu-Teng,Zhang, Xiao-Man,et al. Synthesis, Structures, and Magnetism of Three 1D Mn-III Chains with Oxazoline-Based Ligands[J]. INORGANIC CHEMISTRY,2010,49(13):5868-5875.
APA Zhang, Yan,Wang, Xiu-Teng,Zhang, Xiao-Man,Liu, Tian-Fu,Xu, Wen-Guo,&Gao, Song.(2010).Synthesis, Structures, and Magnetism of Three 1D Mn-III Chains with Oxazoline-Based Ligands.INORGANIC CHEMISTRY,49(13),5868-5875.
MLA Zhang, Yan,et al."Synthesis, Structures, and Magnetism of Three 1D Mn-III Chains with Oxazoline-Based Ligands".INORGANIC CHEMISTRY 49.13(2010):5868-5875.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Yan]'s Articles
[Wang, Xiu-Teng]'s Articles
[Zhang, Xiao-Man]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Yan]'s Articles
[Wang, Xiu-Teng]'s Articles
[Zhang, Xiao-Man]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Yan]'s Articles
[Wang, Xiu-Teng]'s Articles
[Zhang, Xiao-Man]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.