ICCAS OpenIR
Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines
Mo FanYang; Li Fei; Wang JianBo1
2010-09-01
Source PublicationCHINESE SCIENCE BULLETIN
ISSN1001-6538
Volume55Issue:25Pages:2847-2854
AbstractHighly diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to chiral N-sulfinyl imines has been developed. The addition products were further subjected to photo-induced Wolff rearrangement or Rh(II)-catalyzed intramolecular N-H insertion to afford chiral 4,5-disubstituted 2-oxo and 3-oxo pyrrolidines, respectively.
KeywordDiazo Compound Pyrrolidine N-sulfinyl Imine Rhodium Diastereoselective Addition
DOI10.1007/s11434-010-3140-5
Indexed BySCI
Language英语
WOS IDWOS:000281695100017
PublisherSCIENCE PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/69018
Collection中国科学院化学研究所
Corresponding AuthorWang JianBo
Affiliation1.Peking Univ, BNLMS, Beijing 100871, Peoples R China
2.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Mo FanYang,Li Fei,Wang JianBo. Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines[J]. CHINESE SCIENCE BULLETIN,2010,55(25):2847-2854.
APA Mo FanYang,Li Fei,&Wang JianBo.(2010).Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines.CHINESE SCIENCE BULLETIN,55(25),2847-2854.
MLA Mo FanYang,et al."Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines".CHINESE SCIENCE BULLETIN 55.25(2010):2847-2854.
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