ICCAS OpenIR
2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization
Zhang, Min1,2; Zhang, Wenjuan1,2; Xiao, Tianpengfei1,2; Xiang, Jun-Feng1,2; Hao, Xiang1,2; Sun, Wen-Hua1,2,3
2010-04-01
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume320Issue:1-2Pages:92-96
AbstractA series of 2-(1-aryliminopropyl)-1,10-phenanthrolines (L1-L7) and their corresponding iron(II) chlorides (Fe1-Fe7) are synthesized and characterized by elemental and spectroscopic analyses. The molecular structures of 2-[1-(2,6-diisopropy1phenylimino)propyl]-1,10-phenanthroline (13) and (2-11(2,6-diethylphenylimino)propyl]-1,10-phenanthroline (L3) and {2-[1-(2,6-diethylphenylimino)propyl]-1,10-phenanthroline} center dot FeCl(2) (Fe2) are determined by the single crystal X-ray diffraction. All iron complexes, activated with methylaluminoxane (MAO), exhibit high activities in ethylene oligomerization with high selectivity for alpha-olefins produced. Compared with other 2-imino-phenanthrolines, the title complexes show better thermal stability, and their oligomerization products are potentially more useful due to lower contents of butenes and waxes observed. (c) 2010 Elsevier B.V. All rights reserved.
KeywordIron(Ii) Complexes Ethylene Oligomerization 2-ethyl-ketimino-1 10-phenanthroline
DOI10.1016/j.molcata.2010.01.009
Indexed BySCI
Language英语
WOS IDWOS:000276011600014
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68920
Collection中国科学院化学研究所
Corresponding AuthorSun, Wen-Hua
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing Nat Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Min,Zhang, Wenjuan,Xiao, Tianpengfei,et al. 2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2010,320(1-2):92-96.
APA Zhang, Min,Zhang, Wenjuan,Xiao, Tianpengfei,Xiang, Jun-Feng,Hao, Xiang,&Sun, Wen-Hua.(2010).2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,320(1-2),92-96.
MLA Zhang, Min,et al."2-Ethyl-ketimino-1,10-phenanthroline iron(II) complexes as highly active catalysts for ethylene oligomerization".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 320.1-2(2010):92-96.
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