ICCAS OpenIR
Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers
Geng YanHou1,2; Huang Li1,2,3; Wu ShuPeng1,2,3; Wang FoSong1,2
2010-08-01
Source PublicationSCIENCE CHINA-CHEMISTRY
ISSN1674-7291
Volume53Issue:8Pages:1620-1633
AbstractKumada chain-growth polycondensation (KCGP) is a novel method for the synthesis of well-defined conjugated polymers. Because the Ni-catalyst can transfer in an intramolecular process to the propagating chain end, the polymerization follows chain-growth mechanism. With this newly developed method, various conjugated polymers, such as polythiophenes, poly(p-phenylene) (PPP), polypyrrole (PPy), and polyfluorene with controlled molecular weights and relatively narrow polydispersities (PDIs), have been prepared. Especially, the polymerizations for poly(3-alkylthiophene)s (P3ATs), PPP, and PPy exhibited quasi-living characteristics, which allows preparing polymer brushes, fully-conjugated block copolymers, and macroinitiators and macro-reactants for the synthesis of rod-coil block copolymers. In the current review, the progress in this new area is summarized.
KeywordChain Growth Polycondensation Conjugated Polymers Kumada Reaction Block Copolymers Polymer Brush
DOI10.1007/s11426-010-4048-2
Indexed BySCI
Language英语
WOS IDWOS:000281403400003
PublisherSCIENCE PRESS
Citation statistics
Cited Times:42[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68850
Collection中国科学院化学研究所
Corresponding AuthorGeng YanHou
Affiliation1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Geng YanHou,Huang Li,Wu ShuPeng,et al. Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers[J]. SCIENCE CHINA-CHEMISTRY,2010,53(8):1620-1633.
APA Geng YanHou,Huang Li,Wu ShuPeng,&Wang FoSong.(2010).Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers.SCIENCE CHINA-CHEMISTRY,53(8),1620-1633.
MLA Geng YanHou,et al."Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers".SCIENCE CHINA-CHEMISTRY 53.8(2010):1620-1633.
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