ICCAS OpenIR
Vinyl acetate formation in the reaction of acetylene with acetic acid catalyzed by zinc acetate supported on porous carbon spheres
Yan, Feng-Wen; Guo, Cun-Yue; Yan, Fang; Li, Feng-Bo; Qian, Qing-Li; Yuan, Guo-Qing
2010-05-01
Source PublicationRUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
ISSN0036-0244
Volume84Issue:5Pages:796-801
AbstractA kind of porous carbon spheres (PCS) was prepared by the carbonization of poly(vinylidene chloride) synthesized by suspension polymerization. Structure analyses revealed the existence of bumps and holes on the surface of PCS. The PCS, with the pore size between 0.8-1.2 nm, could be used as the support of zinc acetate because of the regular shape, high specific surface area, and good mechanical strength. Vinyl acetate was produced from acetylene and acetic acid using the PCS-supported zinc acetate (PCS-Zn) under mild conditions. In a single-pass operation performed at 220A degrees C, the conversions of acetic acid and acetylene reached 22.6 and 5.3% respectively while the activity of vinyl acetate formation was above 1000 g mol(-1) h(-1).
DOI10.1134/S0036024410050158
Indexed BySCI
Language英语
WOS IDWOS:000277417100015
PublisherMAIK NAUKA/INTERPERIODICA/SPRINGER
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68726
Collection中国科学院化学研究所
Corresponding AuthorYan, Feng-Wen
AffiliationChinese Acad Sci, Inst Chem, New Mat Lab, BNLMS, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yan, Feng-Wen,Guo, Cun-Yue,Yan, Fang,et al. Vinyl acetate formation in the reaction of acetylene with acetic acid catalyzed by zinc acetate supported on porous carbon spheres[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,2010,84(5):796-801.
APA Yan, Feng-Wen,Guo, Cun-Yue,Yan, Fang,Li, Feng-Bo,Qian, Qing-Li,&Yuan, Guo-Qing.(2010).Vinyl acetate formation in the reaction of acetylene with acetic acid catalyzed by zinc acetate supported on porous carbon spheres.RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,84(5),796-801.
MLA Yan, Feng-Wen,et al."Vinyl acetate formation in the reaction of acetylene with acetic acid catalyzed by zinc acetate supported on porous carbon spheres".RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A 84.5(2010):796-801.
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