ICCAS OpenIR
The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes
Sun, Zhenyu; Zhao, Yanfei; Xie, Yun; Tao, Ranting; Zhang, Hongye; Huang, Changliang; Liu, Zhimin
2010
Source PublicationGREEN CHEMISTRY
ISSN1463-9262
Volume12Issue:6Pages:1007-1011
AbstractIn this work, we developed a facile and efficient route to deposit ultra. ne Pt particles onto multi-walled carbon nanotubes (MWNTs) with the aid of tip sonication. The loading of Pt on the MWNTs could attain the very high level of 50 wt% and the size of the Pt particles could be controllably tuned in the range 1.9-3.5 nm with narrow size distributions. The resultant nanocomposites were applied to catalyze the hydrogenation of nitrobenzene under solvent-free conditions. It was demonstrated that the Pt/MWNT catalysts showed excellent activity with a high turnover frequency (e. g., 69 900 h(-1)) as well as superior selectivity to aniline (e. g., >99%) in this reaction.
DOI10.1039/c002391d
Indexed BySCI
Language英语
WOS IDWOS:000278534900013
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:90[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68702
Collection中国科学院化学研究所
Corresponding AuthorLiu, Zhimin
AffiliationChinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Sun, Zhenyu,Zhao, Yanfei,Xie, Yun,et al. The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes[J]. GREEN CHEMISTRY,2010,12(6):1007-1011.
APA Sun, Zhenyu.,Zhao, Yanfei.,Xie, Yun.,Tao, Ranting.,Zhang, Hongye.,...&Liu, Zhimin.(2010).The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes.GREEN CHEMISTRY,12(6),1007-1011.
MLA Sun, Zhenyu,et al."The solvent-free selective hydrogenation of nitrobenzene to aniline: an unexpected catalytic activity of ultrafine Pt nanoparticles deposited on carbon nanotubes".GREEN CHEMISTRY 12.6(2010):1007-1011.
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