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Triptycene-Derived N(H)-Bridged Azacalixarenes: Synthesis, Structure, and Encapsulation of Small Neutral Molecules in the Solid State
Xue, Min1,2; Chen, Chuan-Feng1
2009-11-19
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume11Issue:22Pages:5294-5297
AbstractFour pairs of novel N(H)-bridged azacalixarenes derived from triptycene were synthesized by both one-pot and two-step fragment-coupling approaches. Due to the unique 3D rigid structure of triptycene, the macrocycles all adopted fixed conformations in both solution and solid state. X-ray crystallographic analyses also revealed that the cis isomers with boat conformations showed the capability of encapsulating methanol and acetone molecules inside.
DOI10.1021/ol902246c
Indexed BySCI ; IC
Language英语
WOS IDWOS:000271583000051
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:56[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68472
Collection中国科学院化学研究所
Corresponding AuthorChen, Chuan-Feng
Affiliation1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Xue, Min,Chen, Chuan-Feng. Triptycene-Derived N(H)-Bridged Azacalixarenes: Synthesis, Structure, and Encapsulation of Small Neutral Molecules in the Solid State[J]. ORGANIC LETTERS,2009,11(22):5294-5297.
APA Xue, Min,&Chen, Chuan-Feng.(2009).Triptycene-Derived N(H)-Bridged Azacalixarenes: Synthesis, Structure, and Encapsulation of Small Neutral Molecules in the Solid State.ORGANIC LETTERS,11(22),5294-5297.
MLA Xue, Min,et al."Triptycene-Derived N(H)-Bridged Azacalixarenes: Synthesis, Structure, and Encapsulation of Small Neutral Molecules in the Solid State".ORGANIC LETTERS 11.22(2009):5294-5297.
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