ICCAS OpenIR
Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine
Han, Jing1; Xing, Yong Heng1; Bai, Feng Ying1; Zhang, Xing Jing1; Zeng, Xiao Qing2; Ge, Mao Fa2
2009
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume62Issue:16Pages:2719-2727
AbstractThree new transition metal complexes, [FeII(H2O)6][(C9H7NO3)2FeII] center dot H2O (1), H[K(H2O)3][(C9H7NO3)2CoII] center dot H2O (2), and [CoII(H2O)6][(C9H7NO3)2CoII] center dot H2O (3), with salicylideneglycine have been synthesized and characterized by elemental analysis, IR spectra, UV-Vis spectroscopy, and X-ray crystallography. The structure analyses indicate that the tridentate salicylideneglycine binds through aliphatic nitrogen, phenoxy, and carboxylic oxygen in the anion. There are many inter- and intra-molecular hydrogen bonds among lattice water, the anion, and the cation to form a 3-D network. The thermogravimetric analyses and the quantum chemistry calculations of compounds 1, 2, and 3 are also discussed.
KeywordComplexes Salicylideneglycine Ligand Crystal Structure Hydrogen Bonds
DOI10.1080/00958970902902705
Indexed BySCI
Language英语
WOS IDWOS:000268032900017
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68284
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Han, Jing,Xing, Yong Heng,Bai, Feng Ying,et al. Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine[J]. JOURNAL OF COORDINATION CHEMISTRY,2009,62(16):2719-2727.
APA Han, Jing,Xing, Yong Heng,Bai, Feng Ying,Zhang, Xing Jing,Zeng, Xiao Qing,&Ge, Mao Fa.(2009).Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine.JOURNAL OF COORDINATION CHEMISTRY,62(16),2719-2727.
MLA Han, Jing,et al."Synthesis and characterization of three ionic pairs of Fe(II) and Co(II) complexes with tridentate salicylideneglycine".JOURNAL OF COORDINATION CHEMISTRY 62.16(2009):2719-2727.
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