ICCAS OpenIR
Transcriptive Synthesis of Mg(OH)(2) Hollow Nanospheres and the Non-Equilibrium Shell Fusion Assisted by Catanionic Vesicles
Liu, Fenglin1; Shen, Qiang1; Su, Yunlan2; Han, Shuhua1; Xu, Guiying1; Wang, Dujin2
2009-08-20
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY B
ISSN1520-6106
Volume113Issue:33Pages:11362-11366
AbstractThe oriented attachment of inorganic nanocrystals controlled by adsorbed surfactants can lead to the formation of hollow nanoarchitectures with various well-defined morphologies. In this paper, Mg(OH)(2) hollow nanospheres and the "encapsulated" catanionic vesicles could be simultaneously constructed by using the cationic surfactant of cetyltrimethylammonium hydroxide (CTAOH) and the anionic surfactant of magnesium dodecyl sulfate (Mg(DS)(2)) as reactants at pH 11.0. Therein, the driven forces for the oriented attachment of Mg(OH)(2) particles should involve hydrophobic interactions among pendent surfactants. Similarly, the secondary architectures derived from catanionic surfactant-Mg(OH)(2) hollow nanospheres could also be encountered under nonequilibrium conditions. Interestingly, the coating of Mg(OH)(2) particles facilitated the direct observation of nanosized surfactant self-assemblies and the membrane fusion without using general staining methods. After the crystalline fusion of coating particles, Mg(OH)(2) hollow nanospheres and the correspondingly shell-used Superstructures were obtained, implying a simple and versatile method for the study of lipid membranes and the fabrication of M(OH)(2) (M = divalent metal ions) hollow architectures.
DOI10.1021/jp905525x
Indexed BySCI
Language英语
WOS IDWOS:000268907600002
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68264
Collection中国科学院化学研究所
Corresponding AuthorShen, Qiang
Affiliation1.Shandong Univ, Key Lab Colloid & Interface Chem, Educ Minist, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat,Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, Fenglin,Shen, Qiang,Su, Yunlan,et al. Transcriptive Synthesis of Mg(OH)(2) Hollow Nanospheres and the Non-Equilibrium Shell Fusion Assisted by Catanionic Vesicles[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2009,113(33):11362-11366.
APA Liu, Fenglin,Shen, Qiang,Su, Yunlan,Han, Shuhua,Xu, Guiying,&Wang, Dujin.(2009).Transcriptive Synthesis of Mg(OH)(2) Hollow Nanospheres and the Non-Equilibrium Shell Fusion Assisted by Catanionic Vesicles.JOURNAL OF PHYSICAL CHEMISTRY B,113(33),11362-11366.
MLA Liu, Fenglin,et al."Transcriptive Synthesis of Mg(OH)(2) Hollow Nanospheres and the Non-Equilibrium Shell Fusion Assisted by Catanionic Vesicles".JOURNAL OF PHYSICAL CHEMISTRY B 113.33(2009):11362-11366.
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