ICCAS OpenIR
Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water
Cheng, Yan1; Fan, Honglei1; Wu, Suxiang1; Wang, Qian1; Guo, Jin1,2; Gao, Liang3; Zong, Baoning3; Han, Buxing1
2009
Source PublicationGREEN CHEMISTRY
ISSN1463-9262
Volume11Issue:7Pages:1061-1065
AbstractEnhancing selectivity and an efficient use of feedstocks in chemical reactions using greener methods is an important aspect of green chemistry. In this work, we conducted the hydrogenation of naphthalene to produce tetralin catalyzed by a cheap Fe-Mo based catalyst with and without high temperature water (HTW). The effects of various factors on the reaction, such as density of water, reaction temperature, reaction time and amounts of catalyst, were investigated. It was demonstrated that the addition of water could increase the yield of tetralin and suppress formation of coke effectively. The reaction in the presence of D(2)O indicated that H/D exchange occurred during the reaction process.
DOI10.1039/b904305e
Indexed BySCI
Language英语
WOS IDWOS:000267727800027
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68156
Collection中国科学院化学研究所
Corresponding AuthorCheng, Yan
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.China Univ Min & Technol, Beijing 100190, Peoples R China
3.Res Inst Petr Proc, Beijing 100083, Peoples R China
Recommended Citation
GB/T 7714
Cheng, Yan,Fan, Honglei,Wu, Suxiang,et al. Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water[J]. GREEN CHEMISTRY,2009,11(7):1061-1065.
APA Cheng, Yan.,Fan, Honglei.,Wu, Suxiang.,Wang, Qian.,Guo, Jin.,...&Han, Buxing.(2009).Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water.GREEN CHEMISTRY,11(7),1061-1065.
MLA Cheng, Yan,et al."Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water".GREEN CHEMISTRY 11.7(2009):1061-1065.
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