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Bifunctional catalysis of Morita-Baylis-Hillman (MBH) reaction with chiral primary-tertiary diamine: A non-typical MBH catalytic pathway
Zhang Long3,4; Luo SanZhong1,2; Chen LiuJuan1,2; Li JiuYuan1,2; Cheng JinPei3,4
2009-09-01
Source PublicationSCIENCE IN CHINA SERIES B-CHEMISTRY
ISSN1006-9291
Volume52Issue:9Pages:1300-1308
AbstractA simple primary-tertiary diamine has been explored as a novel catalyst for the Morita-Baylis- Hillman reaction of MVK and aryl aldehydes, and moderate to good chemical yields were obtained. Detailed mechanism study indicated that the diamine acted as a bifunctional cooperation catalyst via a bicyclic enamino-quaternary ammonium intermediate.
KeywordMorita-baylis-hillman Reaction Primary Amine Enamine Iminium Organocatalyst
DOI10.1007/s11426-009-0180-2
Indexed BySCI
Language英语
WOS IDWOS:000270191100003
PublisherSCIENCE PRESS
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Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68142
Collection中国科学院化学研究所
Corresponding AuthorLuo SanZhong
Affiliation1.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
3.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
4.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Zhang Long,Luo SanZhong,Chen LiuJuan,et al. Bifunctional catalysis of Morita-Baylis-Hillman (MBH) reaction with chiral primary-tertiary diamine: A non-typical MBH catalytic pathway[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2009,52(9):1300-1308.
APA Zhang Long,Luo SanZhong,Chen LiuJuan,Li JiuYuan,&Cheng JinPei.(2009).Bifunctional catalysis of Morita-Baylis-Hillman (MBH) reaction with chiral primary-tertiary diamine: A non-typical MBH catalytic pathway.SCIENCE IN CHINA SERIES B-CHEMISTRY,52(9),1300-1308.
MLA Zhang Long,et al."Bifunctional catalysis of Morita-Baylis-Hillman (MBH) reaction with chiral primary-tertiary diamine: A non-typical MBH catalytic pathway".SCIENCE IN CHINA SERIES B-CHEMISTRY 52.9(2009):1300-1308.
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