ICCAS OpenIR
A General Synthesis Approach toward Halloysite-Based Composite Nanotube
Li, Cuiping; Liu, Jiguang; Qu, Xiaozhong; Yang, Zhenzhong
2009-06-05
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
Volume112Issue:5Pages:2647-2655
AbstractWe have demonstrated a general template synthesis halloysite-based composite nanotube. Starting from a parent halloysite nanotiube, polymer composite nanotubes were synthesized by atom transfer radical polymerization (ATRP). The shell thickness and the cavity size of the polymer composite nanotubes were tunable by altering the polymerization time. Composition of the polymer layer could be tuned by the monomers, for example, polystyrene (PS) layer was achieved by AT P of styrene. Sulfonated PS layer (sPS) can be derived by the sulfonation of the PS layer. By specific interactions of desired materials with the sPS gel, a favorable growth of other materials, for example, metallic Ni, conductive polyaniline, inorganic titania is allowed. Besides, sPS can self-catalyze into carbon at high temperature. Thus, the composition of the composite layers can be broadly controlled ranging within metal or metallic compounds, polymer, inorganic, carbon, and their composites. This concept is general and can be extended to other polymeric gels and grown materials, expecting a huge family of composite nanotube. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 112: 2647-2655, 2009
KeywordHaglloysite Nanotube Atrp Polymeric Gel Composite
DOI10.1002/app.29652
Indexed BySCI
Language英语
WOS IDWOS:000265076100007
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:35[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68100
Collection中国科学院化学研究所
Corresponding AuthorYang, Zhenzhong
AffiliationChinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Li, Cuiping,Liu, Jiguang,Qu, Xiaozhong,et al. A General Synthesis Approach toward Halloysite-Based Composite Nanotube[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2009,112(5):2647-2655.
APA Li, Cuiping,Liu, Jiguang,Qu, Xiaozhong,&Yang, Zhenzhong.(2009).A General Synthesis Approach toward Halloysite-Based Composite Nanotube.JOURNAL OF APPLIED POLYMER SCIENCE,112(5),2647-2655.
MLA Li, Cuiping,et al."A General Synthesis Approach toward Halloysite-Based Composite Nanotube".JOURNAL OF APPLIED POLYMER SCIENCE 112.5(2009):2647-2655.
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