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A new polyoxovanadium supramolecular complex [(N(CH2CH2NH3)(3))(2)(V6O18)]center dot 3H(2)O: Synthesis, structure, and thermal properties
Li, J.1; Xing, Y. H.1; Ge, M. F.2; Wang, C. G.1; Li, Z. P.1; Niu, S. Y.1
2009-06-01
Source PublicationJOURNAL OF STRUCTURAL CHEMISTRY
ISSN0022-4766
Volume50Issue:3Pages:532-538
AbstractA new polyoxovanadium supramolecular complex, [(N(CH2CH2NH3)(3))(2)(V6O18)]center dot 3H(2)O (1), was synthesized as a crystalline product from aqueous solution at room temperature. From single crystal X-ray structural analysis, the complex is monoclinic, space group P2(1)/n, with a = 15.878(2) ,b = 11.3309(15) , c = 19.469(3) , beta = 102.244(2)A degrees, V = 3423.0(8) (3), Z = 4, final R = 0.0469. The crystal structure comprises 1D spiral vanadate chain as the oxide moiety, doubly protonated cations of tris(2-aminoethyl)amine (tren) and three lattice molecules of water. There are numerous H bonds in the structure connecting the polyoxovanadium anion moiety, protonated tren cation and lattice water molecules; the average O...O and N...O distances are 2.753 for O-H...O and 2.879 for N-H...O, respectively.
KeywordPolyoxovanadate Complex Hydrogen Bonds Tris(2-aminoethyl)Amine Tren Crystal Structure
DOI10.1007/s10947-009-0081-4
Indexed BySCI
Language英语
WOS IDWOS:000268192200023
PublisherMAIK NAUKA/INTERPERIODICA/SPRINGER
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68044
Collection中国科学院化学研究所
Corresponding AuthorLi, J.
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Li, J.,Xing, Y. H.,Ge, M. F.,et al. A new polyoxovanadium supramolecular complex [(N(CH2CH2NH3)(3))(2)(V6O18)]center dot 3H(2)O: Synthesis, structure, and thermal properties[J]. JOURNAL OF STRUCTURAL CHEMISTRY,2009,50(3):532-538.
APA Li, J.,Xing, Y. H.,Ge, M. F.,Wang, C. G.,Li, Z. P.,&Niu, S. Y..(2009).A new polyoxovanadium supramolecular complex [(N(CH2CH2NH3)(3))(2)(V6O18)]center dot 3H(2)O: Synthesis, structure, and thermal properties.JOURNAL OF STRUCTURAL CHEMISTRY,50(3),532-538.
MLA Li, J.,et al."A new polyoxovanadium supramolecular complex [(N(CH2CH2NH3)(3))(2)(V6O18)]center dot 3H(2)O: Synthesis, structure, and thermal properties".JOURNAL OF STRUCTURAL CHEMISTRY 50.3(2009):532-538.
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