ICCAS OpenIR
Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent
Li, Wei1,2; Jiang, Wei1,2
2009-10-27
Source PublicationMACROMOLECULAR THEORY AND SIMULATIONS
ISSN1022-1344
Volume18Issue:7-8Pages:434-440
AbstractReal-space self-consistent field theory (SCFT) is employed to study the effect of solvent molecular size on the self-assembly of amphiphilic diblock copolymer in selective solvent. The phase diagrams in wide ranges of interaction parameters and solvent molecular size were obtained in present study. The results indicate that the solvent molecular size is a key factor that determines the self-assembly of amphiphilic diblock copolymer. The self-assembled morphology changes from circle-like micelle to line-like micelle, then to loop-like micelle by decreasing the solvent molecular size in a wide range of solvent selectivity. We analyze and discuss this change in terms of the solvent solubility and the entropy contribution.
KeywordAmphiphilic Diblock Copolymer Selectivity Self-assembly Self-consistent Field Theory Solvent Molecular Size
DOI10.1002/mats.200900033
Indexed BySCI
Language英语
WOS IDWOS:000271482900005
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/68026
Collection中国科学院化学研究所
Corresponding AuthorJiang, Wei
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Li, Wei,Jiang, Wei. Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent[J]. MACROMOLECULAR THEORY AND SIMULATIONS,2009,18(7-8):434-440.
APA Li, Wei,&Jiang, Wei.(2009).Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent.MACROMOLECULAR THEORY AND SIMULATIONS,18(7-8),434-440.
MLA Li, Wei,et al."Effect of Solvent Molecular Size on the Self-Assembly of Amphiphilic Diblock Copolymer in Selective Solvent".MACROMOLECULAR THEORY AND SIMULATIONS 18.7-8(2009):434-440.
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