ICCAS OpenIR
Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol
Wang Lei; Ge MaoFa; Wang WeiGang
2009-10-01
Source PublicationCHINESE SCIENCE BULLETIN
ISSN1001-6538
Volume54Issue:20Pages:3808-3812
AbstractThe reaction of a typical unsaturated alcohol, 3-methyl-3-buten-1-ol (MBO331), with Cl atoms, was investigated for the first time. The reaction was investigated using discharged flow-tube coupled with electron impact mass spectrometer. The experiments were performed over the temperature range of 248 K-298 K and at pressure of 1 torr in He as the bath gas. The obtained kinetic data were used to derive the Arrhenius expression: k(1) = (3.47 +/- 1.21) x 10(-11) exp[(599 +/- 69)/T] cm(3) molecule(-1) s(-1). Finally, atmospheric lifetimes of the MBO331 with respect to OH radicals, NO(3) radicals and Cl atoms have been calculated and the atmospheric implications are considered briefly.
KeywordAtmosphereic Chemistry Chloride Atoms Unsaturated Alcohols Gas-phase Reaction Kinetics
DOI10.1007/s11434-009-0439-1
Indexed BySCI
Language英语
WOS IDWOS:000271175500033
PublisherSCIENCE PRESS
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67976
Collection中国科学院化学研究所
Corresponding AuthorGe MaoFa
AffiliationChinese Acad Sci, Inst Chem, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang Lei,Ge MaoFa,Wang WeiGang. Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol[J]. CHINESE SCIENCE BULLETIN,2009,54(20):3808-3812.
APA Wang Lei,Ge MaoFa,&Wang WeiGang.(2009).Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol.CHINESE SCIENCE BULLETIN,54(20),3808-3812.
MLA Wang Lei,et al."Kinetic study of the reaction of chlorine atoms with 3-methyl-3-buten-1-ol".CHINESE SCIENCE BULLETIN 54.20(2009):3808-3812.
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