ICCAS OpenIR
A self-consistent treatment of electron transfer in the limit of strong friction via the mixed quantum classical Liouville method
Shi, Qiang1; Geva, Eitan2,3
2009-07-21
Source PublicationJOURNAL OF CHEMICAL PHYSICS
ISSN0021-9606
Volume131Issue:3
AbstractElectron transfer is investigated at the limit of strong friction. The analysis is based on the generic model of a two-state system bilinearly coupled to a harmonic bath. The dynamics is described within the framework of the mixed quantum classical Liouville (MQCL) equation, which is known to be exact for this model. In the case of zero electronic coupling, it is shown that while the dynamics of the electronic populations can be described by a Markovian quantum Smoluchowski equation, that of the electronic coherences are inherently non-Markovian. A non-Markovian modified Zusman equation is derived in the presence of electronic coupling and shown to be self-consistent in cases where the standard Zusman equation is not.
KeywordCharge Exchange Friction Liouville Equation Reaction Kinetics Theory
DOI10.1063/1.3176509
Indexed BySCI
Language英语
WOS IDWOS:000268206800045
PublisherAMER INST PHYSICS
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67956
Collection中国科学院化学研究所
Corresponding AuthorShi, Qiang
Affiliation1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China
2.Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
3.Univ Michigan, FOCUS Ctr, Ann Arbor, MI 48109 USA
Recommended Citation
GB/T 7714
Shi, Qiang,Geva, Eitan. A self-consistent treatment of electron transfer in the limit of strong friction via the mixed quantum classical Liouville method[J]. JOURNAL OF CHEMICAL PHYSICS,2009,131(3).
APA Shi, Qiang,&Geva, Eitan.(2009).A self-consistent treatment of electron transfer in the limit of strong friction via the mixed quantum classical Liouville method.JOURNAL OF CHEMICAL PHYSICS,131(3).
MLA Shi, Qiang,et al."A self-consistent treatment of electron transfer in the limit of strong friction via the mixed quantum classical Liouville method".JOURNAL OF CHEMICAL PHYSICS 131.3(2009).
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Shi, Qiang]'s Articles
[Geva, Eitan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Shi, Qiang]'s Articles
[Geva, Eitan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Shi, Qiang]'s Articles
[Geva, Eitan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.