ICCAS OpenIR
Distinct Nanostructures from a Molecular Shuttle: Effects of Shuttling Movement on Nanostructural Morphologies
Zhou, Weidong1,2; Xu, Jialiang1,2; Zheng, Haiyan1,2; Yin, Xiaodong1,2; Zuo, Zicheng1,2; Liu, Huibiao1,2; Li, Yuliang1,2
2009-01-09
Source PublicationADVANCED FUNCTIONAL MATERIALS
ISSN1616-301X
Volume19Issue:1Pages:141-149
AbstractA solvent driven molecular shuttle that contains a TCBD chromophore and in which the macrocycle can be positioned close to or far from the TCBD unit with a change of solvent is prepared. Several distinct nanostructures are obtained by control of the shuttling movement of the macrocycle: i) in a mixed solvent of CHCl(3)/n-C(6)H(14) (1/1, v/v), the macrocycle locates at the peptide station, and interlaced nanofibers form as a result of the extended intermolecular dipole-dipole interactions of the TCBD units; ii) in a solvent of dimethyl sulfoxide, the macrocycle moves along the long alkyl-chain, and worm-like nanoparticles form because the macrocycle obstructs the intermolecular dipole-dipole interactions of the TCBD units. This system c firms that the molecular aggregation behaviors can be controlled by the shuttling movement of the macrocycle. Exploitation of the molecular shuttle to control the molecular aggregation behaviors will provide greater understanding in the field of molecular shuttle applications.
DOI10.1002/adfm.200801149
Indexed BySCI
Language英语
WOS IDWOS:000262584800014
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:38[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67892
Collection中国科学院化学研究所
Corresponding AuthorZhou, Weidong
Affiliation1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, BNLMS, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Weidong,Xu, Jialiang,Zheng, Haiyan,et al. Distinct Nanostructures from a Molecular Shuttle: Effects of Shuttling Movement on Nanostructural Morphologies[J]. ADVANCED FUNCTIONAL MATERIALS,2009,19(1):141-149.
APA Zhou, Weidong.,Xu, Jialiang.,Zheng, Haiyan.,Yin, Xiaodong.,Zuo, Zicheng.,...&Li, Yuliang.(2009).Distinct Nanostructures from a Molecular Shuttle: Effects of Shuttling Movement on Nanostructural Morphologies.ADVANCED FUNCTIONAL MATERIALS,19(1),141-149.
MLA Zhou, Weidong,et al."Distinct Nanostructures from a Molecular Shuttle: Effects of Shuttling Movement on Nanostructural Morphologies".ADVANCED FUNCTIONAL MATERIALS 19.1(2009):141-149.
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