ICCAS OpenIR
A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence
Bao, Chunyan; Gan, Quan1,2; Kauffmann, Brice; Jiang, Hua1,2; Huc, Ivan
2009
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
ISSN0947-6539
Volume15Issue:43Pages:11530-11536
AbstractIn this manuscript, we present supramolecular capsules based on a new design relying on both self-assembly and folding of oligomeric strands. We have designed an aromatic amide foldamer in which each monomer encodes three levels of information: a specific cavity size, recognition groups for guest binding, and a propensity to adopt a single or a double helical motif. Thus, a tetradecameric sequence based on four different monomers was encoded so that a wide double helical segment resulting from the hybridization of two strands creates a cavity in which guests, such as 1,10-decanediol, can be bound. Additionally two narrow single helical segments form end-caps and isolate the guest from the solvent. The design, synthesis, solid-state and solution-state characterization of duplex formation and guest binding are presented.
KeywordChirality Helical Structures Molecular Recognition Supramolecular Chemistry X-ray Diffraction
DOI10.1002/chem.200900877
Indexed BySCI ; IC
Language英语
WOS IDWOS:000271992100016
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:33[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67618
Collection中国科学院化学研究所
Corresponding AuthorJiang, Hua
Affiliation1.Univ Bordeaux, Inst Europeen Chim & Biol, CNRS, UMR5248 & UMS 3033, F-33607 Pessac, France
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Bao, Chunyan,Gan, Quan,Kauffmann, Brice,et al. A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence[J]. CHEMISTRY-A EUROPEAN JOURNAL,2009,15(43):11530-11536.
APA Bao, Chunyan,Gan, Quan,Kauffmann, Brice,Jiang, Hua,&Huc, Ivan.(2009).A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence.CHEMISTRY-A EUROPEAN JOURNAL,15(43),11530-11536.
MLA Bao, Chunyan,et al."A Self-Assembled Foldamer Capsule: Combining Single and Double Helical Segments in One Aromatic Amide Sequence".CHEMISTRY-A EUROPEAN JOURNAL 15.43(2009):11530-11536.
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