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Synthetic Study toward the Total Synthesis of Maoecrystal V
Gong, Jianxian1; Lin, Guang2,3; Li, Chuang-chuang1; Yang, Zhen1,2,3
2009-11-05
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume11Issue:21Pages:4770-4773
AbstractA novel and concise approach for the construction of the core structure of maoecrystal V (1) has been developed. Utilizing the lead-mediated arylation of beta-ketoesters and oxidative dearomatization/IMDA reaction as key steps, the two consecutive all-carbon quaternary centers (C-9 and C-10) were constructed in a stereoselective manner. The developed chemistry paves the way for the total synthesis of this fascinating natural product.
DOI10.1021/ol9014392
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000271097100002
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:41[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67478
Collection中国科学院化学研究所
Corresponding AuthorLi, Chuang-chuang
Affiliation1.Peking Univ, Shenzhen Grad Sch, Sch Chem Biol & Biotechnol, Lab Chem Genom, Shenzhen 518055, Peoples R China
2.Peking Univ, Coll Chem, Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China
3.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Gong, Jianxian,Lin, Guang,Li, Chuang-chuang,et al. Synthetic Study toward the Total Synthesis of Maoecrystal V[J]. ORGANIC LETTERS,2009,11(21):4770-4773.
APA Gong, Jianxian,Lin, Guang,Li, Chuang-chuang,&Yang, Zhen.(2009).Synthetic Study toward the Total Synthesis of Maoecrystal V.ORGANIC LETTERS,11(21),4770-4773.
MLA Gong, Jianxian,et al."Synthetic Study toward the Total Synthesis of Maoecrystal V".ORGANIC LETTERS 11.21(2009):4770-4773.
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