ICCAS OpenIR
Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands
Li, Xiaowei1,2,3; Ding, Junqiao1,3; Jin, Weiqun2; Cheng, Yanxiang1,3
2009
Source PublicationINORGANICA CHIMICA ACTA
ISSN0020-1693
Volume362Issue:1Pages:233-237
AbstractTwo mononuclear neutral copper(I) complexes, Cu(L(1))PPh(3) (1), Cu(L(2))(PPh(3))(2) (2) ([L(1)](-) = [{N(C(6)H(3)(i)Pr(2)-2,6)C(H)}(2)CPh](-); [L(2)](-) = [{N(C(6)H(5))C(H)}(2)CPh](-)) have been synthesized and structurally characterized by X-ray crystallography. In complex 1, the copper(I) atom is in a distorted three-coordinate trigonal planar environment, whereas in complex 2 with the less sterically hindered beta-dialdiminato ligand, the copper(I) atom is the centre of a four-coordinate distorted tetrahedron. At room temperature complexes 1 and 2 in a film of PMMA exhibit green emission at 543 and 549 nm with lifetimes of 5.28 and 5.32 ns, respectively. (c) 2007 Elsevier B.V. All rights reserved.
KeywordCopper(i) Complexes Crystal Structures Beta-dialdiminatoes Triphenylphosphine Photoluminescence
DOI10.1016/j.ica.2007.06.024
Indexed BySCI
Language英语
WOS IDWOS:000261274400034
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67474
Collection中国科学院化学研究所
Corresponding AuthorCheng, Yanxiang
Affiliation1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Jilin Univ, Dept Chem, Changchun 130012, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Li, Xiaowei,Ding, Junqiao,Jin, Weiqun,et al. Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands[J]. INORGANICA CHIMICA ACTA,2009,362(1):233-237.
APA Li, Xiaowei,Ding, Junqiao,Jin, Weiqun,&Cheng, Yanxiang.(2009).Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands.INORGANICA CHIMICA ACTA,362(1),233-237.
MLA Li, Xiaowei,et al."Synthesis, crystal structures and spectroscopic properties of copper(I) complexes containing beta-dialdiminato supporting ligands".INORGANICA CHIMICA ACTA 362.1(2009):233-237.
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