ICCAS OpenIR
Hydrodebromination of bromoarenes using Grignard reagents catalyzed by metal ions
Shen, Miao1,2; Sun, Wen-Hua1,2,3
2009-02-01
Source PublicationAPPLIED ORGANOMETALLIC CHEMISTRY
ISSN0268-2605
Volume23Issue:2Pages:51-54
AbstractThe metal salts, FeCl(2)center dot 4H(2)O, FeCl(3), NiCl(2), CoCl(2), CuBr and some iron complexes were found to be efficient catalysts for hydrodebromination of bromoarenes under mild reaction conditions with two equivalents of Grignard reagents. Among them, the iron systems showed the best behavior regarding economic and environmental considerations. All the alkyl Grignard reagents (except CH(3)MgCl) and p-tolylMgBr were promising reductive reagents with the formation of their homo-coupling products. Copyright (c) 2008 John Wiley & Sons, Ltd.
KeywordHydrodebromination Metal Salts/complexes Grignard Reagent Bromoarenes
DOI10.1002/aoc.1470
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000263023900001
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67064
Collection中国科学院化学研究所
Corresponding AuthorSun, Wen-Hua
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Shen, Miao,Sun, Wen-Hua. Hydrodebromination of bromoarenes using Grignard reagents catalyzed by metal ions[J]. APPLIED ORGANOMETALLIC CHEMISTRY,2009,23(2):51-54.
APA Shen, Miao,&Sun, Wen-Hua.(2009).Hydrodebromination of bromoarenes using Grignard reagents catalyzed by metal ions.APPLIED ORGANOMETALLIC CHEMISTRY,23(2),51-54.
MLA Shen, Miao,et al."Hydrodebromination of bromoarenes using Grignard reagents catalyzed by metal ions".APPLIED ORGANOMETALLIC CHEMISTRY 23.2(2009):51-54.
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