ICCAS OpenIR
Synthesis and application of bulky phosphoramidites: highly effective monophosphorus ligands for asymmetric hydrosilylation of styrenes
Zhang, Feng; Fan, Qing-Hua
2009
Source PublicationORGANIC & BIOMOLECULAR CHEMISTRY
ISSN1477-0520
Volume7Issue:21Pages:4470-4474
AbstractA series of bulky monodentate phosphoramidite ligands were synthesized from chiral 3,3'-diaryl substituted BINOL derivatives and achiral or dendritic amines in good yields. Asymmetric hydrosilylation of styrenes with trichlorosilane in the presence of palladium complexes of these bulky ligands gave chiral silanes in high yields with excellent activity and productivity. Oxidation of these chiral silanes with hydrogen peroxide gave the corresponding chiral secondary alcohols in up to 96% ee.
DOI10.1039/b909334f
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000270795700019
PublisherROYAL SOC CHEMISTRY
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/67024
Collection中国科学院化学研究所
Corresponding AuthorFan, Qing-Hua
AffiliationChinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Feng,Fan, Qing-Hua. Synthesis and application of bulky phosphoramidites: highly effective monophosphorus ligands for asymmetric hydrosilylation of styrenes[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2009,7(21):4470-4474.
APA Zhang, Feng,&Fan, Qing-Hua.(2009).Synthesis and application of bulky phosphoramidites: highly effective monophosphorus ligands for asymmetric hydrosilylation of styrenes.ORGANIC & BIOMOLECULAR CHEMISTRY,7(21),4470-4474.
MLA Zhang, Feng,et al."Synthesis and application of bulky phosphoramidites: highly effective monophosphorus ligands for asymmetric hydrosilylation of styrenes".ORGANIC & BIOMOLECULAR CHEMISTRY 7.21(2009):4470-4474.
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