ICCAS OpenIR
Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes
Li, Zhang-Peng1; Xing, Yong-Heng1; Wang, Chun-Guang1; Li, Jing1; Cao, Yun-Zhu1; Zeng, Xiao-Qing2; Ge, Mao-Fa2; Niu, Shu-Yun1
2009
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
Volume635Issue:15Pages:2601-2607
AbstractTwo new oxidovanadium (IV) complexes: TpVO(L-1) (1) and Tp*VO(pzH*)(L-2) (2) [Tp = hydrotris(pyrazolyl)borate, HL1 = 5-methyl-1H-pyrazole-3-carboxylic acid, Tp* = hydrotris(3,5-dimethyl-pyrazolyl)borate,pzH*=3,5-dimethylpyrazole, HL2=5-phenyl-1H-pyra zole-3-carboxylic acid] have been synthesized and characterized by elemental analysis and IR spectroscopy. The single-crystal structures of the complexes shows that the vanadium ion is in a distorted octahedral environment with a N4O2 donor set in each complex. Additionally, hydrogen bonding interaction exits in both complexes. Interestingly, the molecules of I are held together to form a ID hydrogen bonded polymer along the b axis, whereas complex 2 is a hydrogen bonded dimer. In addition, the catalytic activities of complexes 1 and 2 in bromination reactions in phosphate buffer with phenol red as a trap were evaluated primary by UV/Vis spectroscopy. Furthermore, ab initio calculations of complexes 1 and 2 were performed.
KeywordVanadium Haloperoxidases Poly(Pyrazolyl)Borates Carboxylates X-ray Diffraction
DOI10.1002/zaac.200900198
Indexed BySCI
Language英语
WOS IDWOS:000273393800038
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66952
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Bioinorgan Lab, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Li, Zhang-Peng,Xing, Yong-Heng,Wang, Chun-Guang,et al. Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2009,635(15):2601-2607.
APA Li, Zhang-Peng.,Xing, Yong-Heng.,Wang, Chun-Guang.,Li, Jing.,Cao, Yun-Zhu.,...&Niu, Shu-Yun.(2009).Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,635(15),2601-2607.
MLA Li, Zhang-Peng,et al."Haloperoxidase-like Compounds: Synthesis, Structure and Properties of Two New Oxidovanadium-Poly(pyrazolyl)borate-Carboxylate Complexes".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 635.15(2009):2601-2607.
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