ICCAS OpenIR
Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes
Zhang, Hui-Jun1,2; Meng, Tianhao3; Demerseman, Bernard1; Bruneau, Christian1; Xi, Zhenfeng2
2009-10-01
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume11Issue:19Pages:4458-4461
AbstractBy treatment with LiAIH(4),1,4-dicyano-1,4-bis(trimethylsilyi 1,3-dienes underwent a novel hydride-induced nucleophilic intermolecular 1,4-addition to the 4-unsaturated nitrile moiety, followed by an immediate nucleophilic intramolecular 1,2-addition to the remaining CN group, to afford multiply functionalized cyclopentadienes in high isolated yields. These multifunctional (-CN, -NH(2), -SiMe(3), -H) cyclopentadienes are of a rich and interesting reaction chemistry as preliminarily demonstrated by their reaction with ArNCO involving both the substituent and the ring.
DOI10.1021/ol901840c
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000269989100053
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66902
Collection中国科学院化学研究所
Corresponding AuthorBruneau, Christian
Affiliation1.Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France
2.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Hui-Jun,Meng, Tianhao,Demerseman, Bernard,et al. Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes[J]. ORGANIC LETTERS,2009,11(19):4458-4461.
APA Zhang, Hui-Jun,Meng, Tianhao,Demerseman, Bernard,Bruneau, Christian,&Xi, Zhenfeng.(2009).Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes.ORGANIC LETTERS,11(19),4458-4461.
MLA Zhang, Hui-Jun,et al."Hydride-Induced Novel Cyclization of Dienedinitriles Leading to Multifunctionalized Cyclopentadienes".ORGANIC LETTERS 11.19(2009):4458-4461.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, Hui-Jun]'s Articles
[Meng, Tianhao]'s Articles
[Demerseman, Bernard]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, Hui-Jun]'s Articles
[Meng, Tianhao]'s Articles
[Demerseman, Bernard]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, Hui-Jun]'s Articles
[Meng, Tianhao]'s Articles
[Demerseman, Bernard]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.