ICCAS OpenIR
Kinetic study of the reactions of chlorine atoms with ethyl vinyl ether and propyl vinyl ether
Wang, Lei1,2; Ge, Maofa1; Wang, Weigang1
2009-04-29
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume473Issue:1-3Pages:30-33
AbstractKinetic study of the reactions of Cl atoms with EVE and PVE was performed using the absolute rate method over the temperature range 253-298 K at 1 Torr. The obtained Arrhenius expressions were k(EVE) = (8.0 +/- 1.4) x 10 (10)exp[(-349 +/- 21)/T] cm(3) molecule (1) s (1) and k(PVE) = (1.9 +/- 0.3) x 10 (9) exp[(-450 +/- 18)/T] cm(3) molecule (1) s (1). H-atom abstraction is likely to be the main reaction pathway as HCl was detected. The atmospheric lifetimes of EVE and PVE were evaluated, which demonstrates Cl atoms may play an important role for the sink of EVE and PVE. (C) 2009 Elsevier B. V. All rights reserved.
DOI10.1016/j.cplett.2009.03.047
Indexed BySCI
Language英语
WOS IDWOS:000265270800006
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66852
Collection中国科学院化学研究所
Corresponding AuthorGe, Maofa
Affiliation1.Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Lei,Ge, Maofa,Wang, Weigang. Kinetic study of the reactions of chlorine atoms with ethyl vinyl ether and propyl vinyl ether[J]. CHEMICAL PHYSICS LETTERS,2009,473(1-3):30-33.
APA Wang, Lei,Ge, Maofa,&Wang, Weigang.(2009).Kinetic study of the reactions of chlorine atoms with ethyl vinyl ether and propyl vinyl ether.CHEMICAL PHYSICS LETTERS,473(1-3),30-33.
MLA Wang, Lei,et al."Kinetic study of the reactions of chlorine atoms with ethyl vinyl ether and propyl vinyl ether".CHEMICAL PHYSICS LETTERS 473.1-3(2009):30-33.
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