Knowledge Management System Of Institute of Chemistry，CAS
| Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands | |
| Liu, Min; Yang, Zhipei; Sun, Wenhao; Li, Xiuping; Li, Juan; Ma, Jinshi; Yang, Guoqiang | |
| 2009-06-01 | |
| Source Publication | INORGANICA CHIMICA ACTA
 |
| ISSN | 0020-1693 |
| Volume | 362Issue:8Pages:2884-2889 |
| Abstract | Two novel metal-organic frameworks [Zn(3)(BTC)(2)(bbi)(3)](n) (1) (H(3)BTC = 1,3,5-benzenetricarboxylate, bbi = 1,1'-(1,4-butanediyl)bis(imidazole)) and{[Zn(3)(BTC)(2)(bix)(3) center dot 2.5H(2)O]}(n) (2) (bix = 1,4-bis(imidazole-1-ylmethyl) benzene) have been hydrothermally prepared and characterized. Analysis of the structure of 1 displays a 3D framework exhibiting a threefold interpenetration net of identical Zn(1.5)(BTC)(bbi)(1.5) single frameworks. In the structure of 2, BTC(3-) and bix build up infinite tubes extending to a 3D non-interpenetrated porous framework. Moderate fluorescent emissions in the solid state at room temperature were observed in both the compounds. (C) 2009 Elsevier B.V. All rights reserved. |
| Keyword | Metal-organic Frameworks Hydrothermal Synthesis Multiple Building Blocks Crystal Structures Zinc Coordination Polymers |
| DOI | 10.1016/j.ica.2009.01.010 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000265509200054 |
| Publisher | ELSEVIER SCIENCE SA |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.iccas.ac.cn/handle/121111/66806 |
| Collection | 中国科学院化学研究所 |
| Corresponding Author | Yang, Guoqiang |
| Affiliation | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Photochem, Inst Chem, Beijing 100080, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Min,Yang, Zhipei,Sun, Wenhao,et al. Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands[J]. INORGANICA CHIMICA ACTA,2009,362(8):2884-2889. |
| APA | Liu, Min.,Yang, Zhipei.,Sun, Wenhao.,Li, Xiuping.,Li, Juan.,...&Yang, Guoqiang.(2009).Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands.INORGANICA CHIMICA ACTA,362(8),2884-2889. |
| MLA | Liu, Min,et al."Two three-dimensional metal-organic frameworks constructed by multiple building blocks of benzenetricarboxylate and bis(imidazole) ligands".INORGANICA CHIMICA ACTA 362.8(2009):2884-2889. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment