ICCAS OpenIR
Fabrication of self-assembled ultrathin photochromic films containing mixed-addenda polyoxometalates H-5[PMo10V2O40] and 1,10-decanediamine
Wang, Zhongliang1,2; Ma, Ying1; Zhang, Ruili1,2; Xu, Da1,2; Fu, Hongbing1; Yao, Jiannian1
2009-04-01
Source PublicationJOURNAL OF SOLID STATE CHEMISTRY
ISSN0022-4596
Volume182Issue:4Pages:983-988
AbstractA layered phosphovanadomolybdate/1,10-decanediamine (1,10-DAD) self-assembled ultrathin film was fabricated by means of alternating adsorption of mixed-addenda polyoxometalates (POMs) (phosphovanadomolybdate, H-5[PMo10V2O40]) and 1,10-DAD, and its photochromic properties were investigated. It is found that the self-assembled multilayer (SAM) film shows high-photochromic response, excellent photochromic stability and reversibility. The photochromic behavior of the SAM is closely related to the reduction potentials of addenda atoms in mixed-addenda POMs. In the case of photo-reduced mixed-addenda POMs, the electron is localized on the more reducible atom, and the addenda atoms with higher reduction potentials show prior photochromism compared with those with lower reduction potentials. The coloration speed is improved after introduction of V into molybdenum POM. The well-ordered lamellar structure of the film was well maintained during the coloration. (C) 2009 Elsevier Inc. All rights reserved.
KeywordSelf-assembly Inorganic/organic Photochromism Multilayer Polyoxometalates
DOI10.1016/j.jssc.2009.01.014
Indexed BySCI
Language英语
WOS IDWOS:000265122500045
PublisherACADEMIC PRESS INC ELSEVIER SCIENCE
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66738
Collection中国科学院化学研究所
Corresponding AuthorMa, Ying
Affiliation1.Chinese Acad Sci, BNLMS, Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Zhongliang,Ma, Ying,Zhang, Ruili,et al. Fabrication of self-assembled ultrathin photochromic films containing mixed-addenda polyoxometalates H-5[PMo10V2O40] and 1,10-decanediamine[J]. JOURNAL OF SOLID STATE CHEMISTRY,2009,182(4):983-988.
APA Wang, Zhongliang,Ma, Ying,Zhang, Ruili,Xu, Da,Fu, Hongbing,&Yao, Jiannian.(2009).Fabrication of self-assembled ultrathin photochromic films containing mixed-addenda polyoxometalates H-5[PMo10V2O40] and 1,10-decanediamine.JOURNAL OF SOLID STATE CHEMISTRY,182(4),983-988.
MLA Wang, Zhongliang,et al."Fabrication of self-assembled ultrathin photochromic films containing mixed-addenda polyoxometalates H-5[PMo10V2O40] and 1,10-decanediamine".JOURNAL OF SOLID STATE CHEMISTRY 182.4(2009):983-988.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, Zhongliang]'s Articles
[Ma, Ying]'s Articles
[Zhang, Ruili]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, Zhongliang]'s Articles
[Ma, Ying]'s Articles
[Zhang, Ruili]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, Zhongliang]'s Articles
[Ma, Ying]'s Articles
[Zhang, Ruili]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.