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Lanthanide Coordination Polymer Based on the Assembly of Rigid and Flexible Two Types of Carboxylate Ligands, [Eu-2(Suc)(0.5)(BC)(3)(OH)(2)](n), Hydrothermal Synthesis, Structure, and Thermal Decomposition Kinetics Study
Zhang Xing-Jing1; Xing Yong-Heng1; Wang Chun-Guang1; Zeng Xiao-Qing2; Ge Mao-Fa2
2009-03-01
Source PublicationCHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN1001-4861
Volume25Issue:3Pages:407-411
AbstractA lanthanide coordination polymer [Eu-2(Suc)0.5(BC)(3)(OH)(2)](n) (H(2)Suc=succimc acid; HBC=henzoic acid) has been synthesized under hydrothermal conditions and was characterized by X-ray diffraction single crystal structure analysis, elemental analysis and IR spectra. The title complex crystallizes in triclinic, space group P (1) over bar, with a=0.681 1(2) inn, b=1.2062(4) nm, c=1.606 3(5) nm, alpha=69.416(4)degrees, beta=82.855(4)degrees, gamma=74.869(4)degrees, V=1.192(7) nm(3), Z=2. Infinite inorganic walls formed by lanthanide ions, three-bridging hydroxyl group, and an edge-sharing "center dot center dot center dot Eu-O-C-O-Eu center dot center dot center dot" chain, which link to each other through the carbon atoms of the succinate anions and phenyl,groups of the benzoic acid ligands, leading to a two-dimensional open framework structure. The photoluminescent property and the thermogravimetric analysis of the title complex were analysized in detail. CCDC: 644783.
KeywordEuropium(Iii) Coordination Polymer Carboxylate Ligands 2d Structure Hydrothermal Synthesis
Indexed BySCI
Language英语
WOS IDWOS:000264577600006
PublisherCHINESE CHEMICAL SOC
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66600
Collection中国科学院化学研究所
Corresponding AuthorXing Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Liaoning, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang Xing-Jing,Xing Yong-Heng,Wang Chun-Guang,et al. Lanthanide Coordination Polymer Based on the Assembly of Rigid and Flexible Two Types of Carboxylate Ligands, [Eu-2(Suc)(0.5)(BC)(3)(OH)(2)](n), Hydrothermal Synthesis, Structure, and Thermal Decomposition Kinetics Study[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2009,25(3):407-411.
APA Zhang Xing-Jing,Xing Yong-Heng,Wang Chun-Guang,Zeng Xiao-Qing,&Ge Mao-Fa.(2009).Lanthanide Coordination Polymer Based on the Assembly of Rigid and Flexible Two Types of Carboxylate Ligands, [Eu-2(Suc)(0.5)(BC)(3)(OH)(2)](n), Hydrothermal Synthesis, Structure, and Thermal Decomposition Kinetics Study.CHINESE JOURNAL OF INORGANIC CHEMISTRY,25(3),407-411.
MLA Zhang Xing-Jing,et al."Lanthanide Coordination Polymer Based on the Assembly of Rigid and Flexible Two Types of Carboxylate Ligands, [Eu-2(Suc)(0.5)(BC)(3)(OH)(2)](n), Hydrothermal Synthesis, Structure, and Thermal Decomposition Kinetics Study".CHINESE JOURNAL OF INORGANIC CHEMISTRY 25.3(2009):407-411.
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