ICCAS OpenIR
Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification
Zhou, Yinxi; Song, Jinliang; Liang, Shuguang; Hu, Suqin; Liu, Huizhen; Jiang, Tao; Han, Buxing
2009-08-04
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume308Issue:1-2Pages:68-72
AbstractAn efficient synthesis of ethyl methyl carbonate using metal-organic frameworks (MOFs) as Lewis acid catalyst has been realized by the transesterification of dimethyl carbonate and diethyl carbonate. The effects of reaction time, temperature, amount of catalyst and the ratios of substrates on the yield of the objective product were examined. It was demonstrated that MOFs can catalyze the reaction smoothly, and that good yield of ethyl methyl carbonate and high selectivity was achieved under optimized conditions. The catalyst leaching test has shown that the reaction takes place heterogeneously. Moreover, the catalyst can be easily recovered simply by centrifugation and reused over three times without obvious loss of its catalytic activity. (C) 2009 Elsevier B.V. All rights reserved.
KeywordMetal-organic Frameworks Coordination Polymer Transesterification Ethyl mEthyl Carbonate Dimethyl Carbonate Diethyl Carbonate
DOI10.1016/j.molcata.2009.03.027
Indexed BySCI
Language英语
WOS IDWOS:000268359900009
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:52[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66492
Collection中国科学院化学研究所
Corresponding AuthorJiang, Tao
AffiliationChinese Acad Sci, BNLMS, Ctr Mol Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Yinxi,Song, Jinliang,Liang, Shuguang,et al. Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2009,308(1-2):68-72.
APA Zhou, Yinxi.,Song, Jinliang.,Liang, Shuguang.,Hu, Suqin.,Liu, Huizhen.,...&Han, Buxing.(2009).Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,308(1-2),68-72.
MLA Zhou, Yinxi,et al."Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 308.1-2(2009):68-72.
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