ICCAS OpenIR
Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives
Cao, Jing1,2; Lu, Hai-Yan2; Chen, Chuan-Feng1
2009-09-26
Source PublicationTETRAHEDRON
ISSN0040-4020
Volume65Issue:39Pages:8104-8112
AbstractA series of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives have been synthesized. Especially, it was found that if two o-dimethoxybenzene moieties were situated at the same side of the pentiptycene quinones, one of them was only oxidized by excess CAN in aqueous acetonitrile. Moreover, the pentiptycene quinones with unique 3D rigid structure could all self-assemble into a 3D microporous structure in the solid state. For the pentiptycene quinones containing the dimethoxybenzene unit(s) and the quinone group(s) simultaneously, interesting intramolecular charge transfer interactions and electrochemical properties were also shown. These peripheral-substituted pentiptycene quinones and their o-quinone derivatives can be used as new useful building blocks and will find wide applications in material science and host-guest chemistry. (C) 2009 Elsevier Ltd. All rights reserved.
KeywordPentiptycene Quinones Synthesis And Structure Self-assembly In The Solid State Photo-physical Property Electrochemistry Property
DOI10.1016/j.tet.2009.07.090
Indexed BySCI ; IC
Language英语
WOS IDWOS:000270121400004
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66436
Collection中国科学院化学研究所
Corresponding AuthorChen, Chuan-Feng
Affiliation1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Cao, Jing,Lu, Hai-Yan,Chen, Chuan-Feng. Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives[J]. TETRAHEDRON,2009,65(39):8104-8112.
APA Cao, Jing,Lu, Hai-Yan,&Chen, Chuan-Feng.(2009).Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives.TETRAHEDRON,65(39),8104-8112.
MLA Cao, Jing,et al."Synthesis, structures, and properties of peripheral o-dimethoxy-substituted pentiptycene quinones and their o-quinone derivatives".TETRAHEDRON 65.39(2009):8104-8112.
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