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Multifunctional Fluorene-Based Oligomers with Novel Spiro-Annulated Triarylamine: Efficient, Stable Deep-Blue Electroluminescence, Good Hole Injection, and Transporting Materials with Very High T-g
Jiang, Zuoquan1; Liu, Zhongyin1; Yang, Chuluo1; Zhong, Cheng1; Qin, Jingui1; Yu, Gui2; Liu, Yunqi2
2009-12-23
Source PublicationADVANCED FUNCTIONAL MATERIALS
ISSN1616-301X
Volume19Issue:24Pages:3987-3995
AbstractA series of fluorene-based oligomers with novel spiro-annulated triarylamine structures, namely DFSTPA, TFSTPA, and TFSDTC, are synthesized by a Suzuki cross-coupling reaction. The spiro-configuration molecular structures lead to very high glass transition temperatures (197-253 degrees C) and weak intermolecular interactions, and consequently the structures retain good morphological stability and high fluorescence quantum efficiencies (0.69-0.98). This molecular design simultaneously solves the spectral stability problems and hole-injection and transport issues for fluorene-based blue-light-emitting materials. Simple double-layer electroluminescence (EL) devices with a configuration of ITO/TFSTPA (device A) or TFSDTC (device B)/TPBI/LiF/Al, where TFSTPA and TFSDTC serve as hole-transporting blue-light-emitting materials, show a deep-blue emission with a peak around 432 nm, and CIE coordinates of (0.17, 0.12) for TFSTPA and (0.16, 0.07) for TFSDTC, respectively, which are very close to the National Television System Committee (NTSC) standard for blue (0.15, 0.07). The maximum current efficiency/external quantum efficiencies are 1.63 cd A(-1)/1.6% for device A and 1.91 cd A(-1)/2.7% for device B, respectively. In addition, a device with the structure ITO/DFSTPA/Alq(3)/LiF/Al, where DFSTPA acts as both the hole-injection and -transporting material, is shown to achieve a good performance, with a maximum luminance of 14 047 cd m(-2), and a maximum current efficiency of 5.56 cd A(-1). These values are significantly higher than those of devices based on commonly used N,N'-di(1-naphthyl)-N,N'-diphenyl-[1,1'-biphenyl]-4,4'-diamine (NPB) as the hole-transporting layer (11738 cd m(-2) and 3.97 cd A(-1)) under identical device conditions.
DOI10.1002/adfm.200901534
Indexed BySCI
Language英语
WOS IDWOS:000273359600019
PublisherWILEY-BLACKWELL
Citation statistics
Cited Times:127[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66432
Collection中国科学院化学研究所
Corresponding AuthorJiang, Zuoquan
Affiliation1.Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Jiang, Zuoquan,Liu, Zhongyin,Yang, Chuluo,et al. Multifunctional Fluorene-Based Oligomers with Novel Spiro-Annulated Triarylamine: Efficient, Stable Deep-Blue Electroluminescence, Good Hole Injection, and Transporting Materials with Very High T-g[J]. ADVANCED FUNCTIONAL MATERIALS,2009,19(24):3987-3995.
APA Jiang, Zuoquan.,Liu, Zhongyin.,Yang, Chuluo.,Zhong, Cheng.,Qin, Jingui.,...&Liu, Yunqi.(2009).Multifunctional Fluorene-Based Oligomers with Novel Spiro-Annulated Triarylamine: Efficient, Stable Deep-Blue Electroluminescence, Good Hole Injection, and Transporting Materials with Very High T-g.ADVANCED FUNCTIONAL MATERIALS,19(24),3987-3995.
MLA Jiang, Zuoquan,et al."Multifunctional Fluorene-Based Oligomers with Novel Spiro-Annulated Triarylamine: Efficient, Stable Deep-Blue Electroluminescence, Good Hole Injection, and Transporting Materials with Very High T-g".ADVANCED FUNCTIONAL MATERIALS 19.24(2009):3987-3995.
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