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A Series of Three-Dimensional Lanthanide-Rigid-Flexible Frameworks: Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid
Wang, Chun-Guang1; Xing, Yong-Heng1; Li, Zhang-Peng1; Li, Jing1; Zeng, Xiao-Qing2; Ge, Mao-Fa2; Niu, Shu-Yun1
2009-03-01
Source PublicationCRYSTAL GROWTH & DESIGN
ISSN1528-7483
Volume9Issue:3Pages:1525-1530
AbstractA new series of lanthanide coordination polymers, namely, [Ln(ad)(0.5)(2,5-pydc)(H2O)] (Ln = Eu (1), Pr (2), Nd (3), Sm (4), Tb(5); H(2)ad = adipic acid; 2,5-H(2)Pydc = 2,5-pyridine dicarboxylic acid), have been synthesized hydrothermally from the self-assembly of the lanthanide ions (Ln(3+)) with the flexible adipic dicarboxylate ligand and the rigid 2,5-pyridine dicarboxylic acid ligand. All of them were characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Structural analyses reveal that all five complexes have intricate three-dimensional net-structures, and in these complexes, they were crystallized in monoclinic space group P2(1)/c. In addition, the phase purities of the bulk samples were identified by X-ray powder diffraction. The thermogravimetric analysis of I and photoluminescent properties of 1 and 5 are discussed in detail.
DOI10.1021/cg801157k
Indexed BySCI
Language英语
WOS IDWOS:000263921300049
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:90[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66362
Collection中国科学院化学研究所
Corresponding AuthorXing, Yong-Heng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Chun-Guang,Xing, Yong-Heng,Li, Zhang-Peng,et al. A Series of Three-Dimensional Lanthanide-Rigid-Flexible Frameworks: Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid[J]. CRYSTAL GROWTH & DESIGN,2009,9(3):1525-1530.
APA Wang, Chun-Guang.,Xing, Yong-Heng.,Li, Zhang-Peng.,Li, Jing.,Zeng, Xiao-Qing.,...&Niu, Shu-Yun.(2009).A Series of Three-Dimensional Lanthanide-Rigid-Flexible Frameworks: Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid.CRYSTAL GROWTH & DESIGN,9(3),1525-1530.
MLA Wang, Chun-Guang,et al."A Series of Three-Dimensional Lanthanide-Rigid-Flexible Frameworks: Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid".CRYSTAL GROWTH & DESIGN 9.3(2009):1525-1530.
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