ICCAS OpenIR
Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends
Wu, Tongfei1,2; Xie, Tingxiu3; Yang, Guisheng1,3
2009-01-05
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
Volume111Issue:1Pages:101-107
AbstractWe successfully synthesized monomer casting polyamide 6 (MCPA6)/poly(methyl methacrylate) (PMMA) blends in two steps: (1) radical polymerization of methyl methacrylate in epsilon-caprolactam and (2) anionic ring-opening polymerization of this epsilon-caprolactam solution. The influence of PMMA on the crystallization behavior of MCPA6 was studied with differential scanning calorimetry and X-ray diffraction, which showed that PMMA could act as a heterogeneous nucleation agent and favored the formation of the gamma-crystalline form. The rheological properties were also studied and indicated that PMMA reduced the interaction between MCPA6 chains by lowering the density of hydrogen bonding. This study used a novel and convenient method to prepare microporous MCPA6/PMMA particles that involved removing the continuous phase. Their surface area and thermal stability were characterized by the Brunauer-Emmett-Teller method and thermogravimetric analysis, respectively. (C) 2008 Wiley Periodicals, Inc. J Appl Polym Sci 111: 101-107, 2009
KeywordBlends Compatibility Crystallization
DOI10.1002/app.29014
Indexed BySCI
Language英语
WOS IDWOS:000261152400013
PublisherJOHN WILEY & SONS INC
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66266
Collection中国科学院化学研究所
Corresponding AuthorYang, Guisheng
Affiliation1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Technol, Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China
Recommended Citation
GB/T 7714
Wu, Tongfei,Xie, Tingxiu,Yang, Guisheng. Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2009,111(1):101-107.
APA Wu, Tongfei,Xie, Tingxiu,&Yang, Guisheng.(2009).Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends.JOURNAL OF APPLIED POLYMER SCIENCE,111(1),101-107.
MLA Wu, Tongfei,et al."Synthesis and Properties of Monomer Casting Polyamide 6/Poly(methyl methacrylate) Blends".JOURNAL OF APPLIED POLYMER SCIENCE 111.1(2009):101-107.
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