ICCAS OpenIR
A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction
Yan, Jie1; Zhao, Haiyan1; Li, Zhangpeng1; Xing, Yongheng1; Zeng, Xiaoqing2; Ge, Maofa2; Niu, Shuyun1
2009-12-01
Source PublicationJOURNAL OF CLUSTER SCIENCE
ISSN1040-7278
Volume20Issue:4Pages:717-724
AbstractA self-assembled 3D hydrogen bonded network constructed from polyoxovanadate and organic substrate [V10O28][(CH3)(2)NH2](4)(imidazolium)(2) (1) has been synthesized at room temperature and characterized by elemental analysis, IR and single-crystal X-ray diffraction. The structure of 1 can be regarded as being linked by the dimethylammonium cations of the decavanadate clusters to produce an interesting 3D network with a 4(12)6(3) topology. In the resulting network, there exist one-dimensional channels along the a-axis, in which the imidazolium cations filled the channels. These imidazolium cations are involved in intermolecular hydrogen bonds of the types N-H center dot center dot center dot O and C-H center dot center dot center dot O, which seem to be main forces to stabilize the holistic structure.
KeywordPolyoxovanadate Hydrogen Bond Crystal Structure Topology
DOI10.1007/s10876-009-0274-1
Indexed BySCI
Language英语
WOS IDWOS:000272616700008
PublisherSPRINGER/PLENUM PUBLISHERS
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/66170
Collection中国科学院化学研究所
Corresponding AuthorXing, Yongheng
Affiliation1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yan, Jie,Zhao, Haiyan,Li, Zhangpeng,et al. A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction[J]. JOURNAL OF CLUSTER SCIENCE,2009,20(4):717-724.
APA Yan, Jie.,Zhao, Haiyan.,Li, Zhangpeng.,Xing, Yongheng.,Zeng, Xiaoqing.,...&Niu, Shuyun.(2009).A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction.JOURNAL OF CLUSTER SCIENCE,20(4),717-724.
MLA Yan, Jie,et al."A Self-Assembled 3D Hydrogen Bonded Network Constructed from Polyoxovanadate and Protonated Organic Substrate With a Solvent Hydrolysis Reaction".JOURNAL OF CLUSTER SCIENCE 20.4(2009):717-724.
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