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New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes
Su, Jie; Wang, Yingxia; Li, Weihong; Yang, Sihai; Li, Guobao; Liao, Fuhui; Lin, Jianhua
2009-11-26
Source PublicationJOURNAL OF MOLECULAR STRUCTURE
ISSN0022-2860
Volume937Issue:1-3Pages:39-43
AbstractTwo new double formates, Na3M(HCOO)(6) (M = Ga, In), have been synthesized by using quasi-solvothermal method. Both Compounds are iscistructural, crystallizing in orthorhombic space group Pccn, with lattice parameters a = 14.6279(5) angstrom, b = 6.2607(1) angstrom, and c = 13.5132(4) angstrom for Na3Ga(HCOO)(6) and a = 14.6054(5) angstrom, b = 6.4160(1) angstrom, and c = 13.9444(3) angstrom for Na3In(HCOO)(6). The structure takes a three-dimensional framework consisting of MO6 and NaO6 octahedra which are connected in edge- and corner-sharing modes. Regarding to the linkage of octahedra, the framework could be considered as a diamond net. The formates in the structure bridge the metal octahedra in an unusual 4.22 connection mode. IR spectroscopy and elemental analysis support the Structure characterization. Thermal decomposition process was also studied by TG and X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.
KeywordGallium Formate Indium Formate Sodium Formate Double Formates X-ray Crystal Structure
DOI10.1016/j.molstruc.2009.08.009
Indexed BySCI
Language英语
WOS IDWOS:000271838100006
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65964
Collection中国科学院化学研究所
Corresponding AuthorWang, Yingxia
AffiliationPeking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Su, Jie,Wang, Yingxia,Li, Weihong,et al. New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes[J]. JOURNAL OF MOLECULAR STRUCTURE,2009,937(1-3):39-43.
APA Su, Jie.,Wang, Yingxia.,Li, Weihong.,Yang, Sihai.,Li, Guobao.,...&Lin, Jianhua.(2009).New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes.JOURNAL OF MOLECULAR STRUCTURE,937(1-3),39-43.
MLA Su, Jie,et al."New double formates Na3M(HCOO)(6) (M = Ga, In) with diamond-like metal framework: Synthesis, structure and coordination modes".JOURNAL OF MOLECULAR STRUCTURE 937.1-3(2009):39-43.
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