ICCAS OpenIR
Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule
He, Jun1; Yang, Chen1; Xu, Zhengtao1; Zeller, Matthias2; Hunter, Allen D.2; Lin, Jianhua3
2009-07-01
Source PublicationJOURNAL OF SOLID STATE CHEMISTRY
ISSN0022-4596
Volume182Issue:7Pages:1821-1826
AbstractThe simple and easy-to-prepare bifunctional molecule 2,5-dimercapto-1,4-benzenedicarboxylic acid (H(4)DMBD) interacts with the increasingly harder metal ions of Cu(+), Pb(2+) and Eu(3+) to form the coordination networks Of Cu(6)(DMBD)(3)(en)(4)(Hen)(6), (1), Pb(2)(DMBD)(en)(2) (2) and Eu(2)(H(2)DMBD)(3)(DEF)(4) (3), where the carboxyl and thiol groups bind with distinct preference to the hard and soft metal ions, respectively. Notably, 1 features uncoordinated carboxylate groups and Cu(3) cluster units integrated via the thiolate groups into an extended network with significant interaction between the metal centers and the organic molecules; 2 features a 2D coordination net based On the mercapto and carboxylic groups all bonded to the Pb(2+) ions; 3 features free-standing thiol groups inside the channels of a metal-carboxylate-based network. This study illustrates the rich solid state structural features and potential functions offered by the carboxyl-thiol combination. (C) 2009 Elsevier Inc. All rights reserved.
KeywordMetal-thiolate Networks Coordination Networks Bifunctional Ligands Crystal Engineering
DOI10.1016/j.jssc.2009.04.024
Indexed BySCI
Language英语
WOS IDWOS:000267717600032
PublisherACADEMIC PRESS INC ELSEVIER SCIENCE
Citation statistics
Cited Times:36[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65926
Collection中国科学院化学研究所
Corresponding AuthorXu, Zhengtao
Affiliation1.City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China
2.Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
3.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
He, Jun,Yang, Chen,Xu, Zhengtao,et al. Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule[J]. JOURNAL OF SOLID STATE CHEMISTRY,2009,182(7):1821-1826.
APA He, Jun,Yang, Chen,Xu, Zhengtao,Zeller, Matthias,Hunter, Allen D.,&Lin, Jianhua.(2009).Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule.JOURNAL OF SOLID STATE CHEMISTRY,182(7),1821-1826.
MLA He, Jun,et al."Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule".JOURNAL OF SOLID STATE CHEMISTRY 182.7(2009):1821-1826.
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