ICCAS OpenIR
New Cholesterol-Based Gelators with Maleimide Unit and the Relevant Michael Adducts: Chemoresponsive Organogels
Chen, Qun1,2; Zhang, Deqing1; Zhang, Guanxin1; Zhu, Daoben1
2009-10-06
Source PublicationLANGMUIR
ISSN0743-7463
Volume25Issue:19Pages:11436-11441
AbstractCompound I containing cholesteryl and maleimide units can gel a few organic solvents such as cyclohexane. It is interesting to note that the gel-sol transition can be triggered by addition of trace amounts of thiol and triethylamine. In this regard, we Successfully demonstrate the proof of principle for designing chemo responsive gels by incorporating the reactive groups into the gelators. Additionally, the Michael adducts 2 and 3 were prepared. Compounds 2 and 3 call also gel several organic solvents. The results also show that slight molecular structural variation has a large effect oil the gelation ability of the Compound. These organogels were characterized with SEM, AFM, CD, and XRD. Interestingly, gelation-induced CD spectra were observed for gels of 1, 2, and 3.
DOI10.1021/la9016257
Indexed BySCI
Language英语
WOS IDWOS:000270136900040
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65922
Collection中国科学院化学研究所
Corresponding AuthorZhang, Deqing
Affiliation1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Organ Solids Lab, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Chen, Qun,Zhang, Deqing,Zhang, Guanxin,et al. New Cholesterol-Based Gelators with Maleimide Unit and the Relevant Michael Adducts: Chemoresponsive Organogels[J]. LANGMUIR,2009,25(19):11436-11441.
APA Chen, Qun,Zhang, Deqing,Zhang, Guanxin,&Zhu, Daoben.(2009).New Cholesterol-Based Gelators with Maleimide Unit and the Relevant Michael Adducts: Chemoresponsive Organogels.LANGMUIR,25(19),11436-11441.
MLA Chen, Qun,et al."New Cholesterol-Based Gelators with Maleimide Unit and the Relevant Michael Adducts: Chemoresponsive Organogels".LANGMUIR 25.19(2009):11436-11441.
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