ICCAS OpenIR
Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule
Yin, Xiaodong1; Li, Yongjun1; Li, Yuliang1; Zhu, Yulan3; Tang, Xueling3; Zheng, Haiyan1,2; Zhu, Daoben1
2009-10-03
Source PublicationTETRAHEDRON
ISSN0040-4020
Volume65Issue:40Pages:8373-8377
AbstractA new type of donor-acceptor molecule DiFc-B combined ferrocene and BODIPY unit has been synthesized, and the NMR spectra, photophysical property, and electrochemical property were studied. The in situ spectro-electrochemical experiment was carried out, a notable absorption change had been observed under oxidative potential, and a recovery could happen under reductive potential and this process could repeat for several times. Such a phenomenon also happened when oxidative metal ion was added into the solution of DiFc-B. In order to study the mechanism of the electrochromism, the theoretical calculation was performed, and the result shows a D (ferrocene)-pi-A (BODIPY) system. The energy gap between the HOMO and LUMO had a good consistence with the electrochemical experiment and UV-vis data. The calculation of the frontier orbital belonging to the cation state of Difc-B shows the directional change of the D-pi-A system, which supplied a theoretical basis of the electrochromism. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.
KeywordElectrochromism Organic Metallic Compound Density Functional Theoretical Calculation Charge Transfer
DOI10.1016/j.tet.2009.08.008
Indexed BySCI ; IC
Language英语
WOS IDWOS:000269995900009
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:44[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65786
Collection中国科学院化学研究所
Corresponding AuthorLi, Yuliang
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, BNLMS,CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China
3.Huaiyin Teachers Coll, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China
Recommended Citation
GB/T 7714
Yin, Xiaodong,Li, Yongjun,Li, Yuliang,et al. Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule[J]. TETRAHEDRON,2009,65(40):8373-8377.
APA Yin, Xiaodong.,Li, Yongjun.,Li, Yuliang.,Zhu, Yulan.,Tang, Xueling.,...&Zhu, Daoben.(2009).Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule.TETRAHEDRON,65(40),8373-8377.
MLA Yin, Xiaodong,et al."Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule".TETRAHEDRON 65.40(2009):8373-8377.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yin, Xiaodong]'s Articles
[Li, Yongjun]'s Articles
[Li, Yuliang]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yin, Xiaodong]'s Articles
[Li, Yongjun]'s Articles
[Li, Yuliang]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yin, Xiaodong]'s Articles
[Li, Yongjun]'s Articles
[Li, Yuliang]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.