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Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization
Xiao, Liwei2; Jie, Suyun1; Song, Yingxia1; Cao, Xiaoping2; Sun, Wen-Hua1,2
2008-12-15
Source PublicationJOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN0022-328X
Volume693Issue:26Pages:3858-3866
AbstractThe 2-alkoxyimidate-1,10-phenanthroline complexes of manganese, cobalt and nickel have been synthesized by the reaction of 2-cyano-1,10-phenanthroline with metal dichloride in the corresponding alcohol. The metal complexes bearing two 2-cyano- 1,10-phenanthrolines were isolated in non-protonic solvent as the coordination around metal core with two ligands and two chlorides. The alkoxyimidation of nitrile linked on ligand was speeded in forming the 2-alkoxyimidate-1,10-phenanthrolinyl metal complexes. All the complexes have been characterized by FT-IR spectra and elemental analysis, and some of their structures have also been confirmed by single-crystal X-ray diffraction analysis. All the metal complexes were evaluated in the catalytic oligomerization of ethylene with some alkylaluminums as co-catalyst; in which manganese complexes were less active, cobalt complexes showed low to moderate activities, and nickel complexes gave moderate to good activities. (C) 2008 Elsevier B.V. All rights reserved.
KeywordManganese Cobalt Nickel Ethylene Oligomerization 2-alkoxyimidate-1 2-cyano-1 10-phenanthroline 10-phenanthroline
DOI10.1016/j.jorganchem.2008.09.052
Indexed BySCI ; IC
Language英语
WOS IDWOS:000261162900011
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/65656
Collection中国科学院化学研究所
Corresponding AuthorSun, Wen-Hua
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China
2.Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Xiao, Liwei,Jie, Suyun,Song, Yingxia,et al. Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2008,693(26):3858-3866.
APA Xiao, Liwei,Jie, Suyun,Song, Yingxia,Cao, Xiaoping,&Sun, Wen-Hua.(2008).Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization.JOURNAL OF ORGANOMETALLIC CHEMISTRY,693(26),3858-3866.
MLA Xiao, Liwei,et al."Transformation of 2-alkoxyimidate-1,10-phenanthroline) metal (Mn2+, Co2+ and Ni2+) chlorides from bis(2-cyano-1,10-phenanthroline) metal chlorides: Syntheses, characterizations and their catalytic behavior toward ethylene oligomerization".JOURNAL OF ORGANOMETALLIC CHEMISTRY 693.26(2008):3858-3866.
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